Аннотация
The anionic tantalum complex (ItBuH)[Ta(NMe2)3Cl3] (I) is synthesized by the reaction of [Ta(NMe2)3Cl2]2 with N-heterocyclic carbene ItBu and is isolated as two crystalline modifications (Ia and Ib). Its fluoride analogue (ItBuH)[Ta(NMe2)3F3] (II) is synthesized by the reaction of Ta(NMe2)5 with (ItBuH)BF4. The structures of the complexes are determined by X-ray diffraction analysis (CIF files CCDC nos. 1977540 (Ia), 1977541 (Ib), and 1977542 (II)).
Язык оригинала | английский |
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Страницы (с-по) | 593-599 |
Число страниц | 7 |
Журнал | Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
Том | 46 |
Номер выпуска | 9 |
DOI | |
Состояние | Опубликовано - 1 сен 2020 |