Mixed [{β-B-SbM9O33}2(µ-MO2)2]14− (M = W, Mo) polyoxoanions

Alexandra A. Shmakova; Victoria V. Volchek; Rishat R. Shiriyazdanov; Albina R. Karimova; Pavel A. Abramov; Maxim N. Sokolov

doi:10.1016/j.poly.2018.12.047

Mixed [{β-B-SbM₉O₃₃}₂(µ-MO₂)₂]¹⁴⁻ (M = W, Mo) polyoxoanions

Alexandra A. Shmakova, Victoria V. Volchek, Rishat R. Shiriyazdanov, Albina R. Karimova, Pavel A. Abramov, Maxim N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья

1 Цитирования (Scopus)

Аннотация

The reaction of Na₉[α-B-SbW₉O₃₃]·19.5H₂O with Na₂MoO₄ results in the formation of new mixed W/Mo polyanions, isolated as various salts, (Me₂NH₂)₁₁Na[Sb₂Mo₄W₁₆O₇₀(MoO₂)]·17H₂O (1a) and (Me₄N)₆Na₅[Sb₂Mo_3.5W_16.5O₇₀(MoO₂)_1.5]·27H₂O (2). Both 1a and 2 were characterized by XRD, XRPD, IR, Raman spectra and elemental analysis. According to HPLC-ICP-AES, both 1a and 2 equilibrate in aqueous solutions with the constituent {SbM₉} anions.

Язык оригинала	английский
Страницы (с-по)	78-83
Число страниц	6
Журнал	Polyhedron
Том	161
DOI	https://doi.org/10.1016/j.poly.2018.12.047
Состояние	Опубликовано - 15 мар 2019

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10.1016/j.poly.2018.12.047

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Цитировать

Shmakova, A. A., Volchek, V. V., Shiriyazdanov, R. R., Karimova, A. R., Abramov, P. A., & Sokolov, M. N. (2019). Mixed [{β-B-SbM₉O₃₃}₂(µ-MO₂)₂]¹⁴⁻ (M = W, Mo) polyoxoanions. Polyhedron, 161, 78-83. https://doi.org/10.1016/j.poly.2018.12.047

@article{e4b965b9406740929a2becee4be7993b,

title = "Mixed [{β-B-SbM9O33}2(µ-MO2)2]14− (M = W, Mo) polyoxoanions",

abstract = "The reaction of Na9[α-B-SbW9O33]·19.5H2O with Na2MoO4 results in the formation of new mixed W/Mo polyanions, isolated as various salts, (Me2NH2)11Na[Sb2Mo4W16O70(MoO2)]·17H2O (1a) and (Me4N)6Na5[Sb2Mo3.5W16.5O70(MoO2)1.5]·27H2O (2). Both 1a and 2 were characterized by XRD, XRPD, IR, Raman spectra and elemental analysis. According to HPLC-ICP-AES, both 1a and 2 equilibrate in aqueous solutions with the constituent {SbM9} anions.",

keywords = "Mixed W/Mo polyoxoanions, Raman spectroscopy, Solution behavior, Structural changes, XRD, OXIDATION, COMPLEXES, STRUCTURAL-CHARACTERIZATION, CRYSTAL-STRUCTURES, IDENTIFICATION, FAMILY, NMR, CYCLOHEXENE, HETEROPOLYMETALATE CLUSTERS, POLYOXOMETALATE",

author = "Shmakova, {Alexandra A.} and Volchek, {Victoria V.} and Shiriyazdanov, {Rishat R.} and Karimova, {Albina R.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",

year = "2019",

month = mar,

day = "15",

doi = "10.1016/j.poly.2018.12.047",

language = "English",

volume = "161",

pages = "78--83",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

}

Mixed [{β-B-SbM₉O₃₃}₂(µ-MO₂)₂]¹⁴⁻ (M = W, Mo) polyoxoanions. / Shmakova, Alexandra A.; Volchek, Victoria V.; Shiriyazdanov, Rishat R.; Karimova, Albina R.; Abramov, Pavel A.; Sokolov, Maxim N.

В: Polyhedron, Том 161, 15.03.2019, стр. 78-83.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Mixed [{β-B-SbM9O33}2(µ-MO2)2]14− (M = W, Mo) polyoxoanions

AU - Shmakova, Alexandra A.

AU - Volchek, Victoria V.

AU - Shiriyazdanov, Rishat R.

AU - Karimova, Albina R.

AU - Abramov, Pavel A.

AU - Sokolov, Maxim N.

PY - 2019/3/15

Y1 - 2019/3/15

N2 - The reaction of Na9[α-B-SbW9O33]·19.5H2O with Na2MoO4 results in the formation of new mixed W/Mo polyanions, isolated as various salts, (Me2NH2)11Na[Sb2Mo4W16O70(MoO2)]·17H2O (1a) and (Me4N)6Na5[Sb2Mo3.5W16.5O70(MoO2)1.5]·27H2O (2). Both 1a and 2 were characterized by XRD, XRPD, IR, Raman spectra and elemental analysis. According to HPLC-ICP-AES, both 1a and 2 equilibrate in aqueous solutions with the constituent {SbM9} anions.

AB - The reaction of Na9[α-B-SbW9O33]·19.5H2O with Na2MoO4 results in the formation of new mixed W/Mo polyanions, isolated as various salts, (Me2NH2)11Na[Sb2Mo4W16O70(MoO2)]·17H2O (1a) and (Me4N)6Na5[Sb2Mo3.5W16.5O70(MoO2)1.5]·27H2O (2). Both 1a and 2 were characterized by XRD, XRPD, IR, Raman spectra and elemental analysis. According to HPLC-ICP-AES, both 1a and 2 equilibrate in aqueous solutions with the constituent {SbM9} anions.

KW - Mixed W/Mo polyoxoanions

KW - Raman spectroscopy

KW - Solution behavior

KW - Structural changes

KW - XRD

KW - OXIDATION

KW - COMPLEXES

KW - STRUCTURAL-CHARACTERIZATION

KW - CRYSTAL-STRUCTURES

KW - IDENTIFICATION

KW - FAMILY

KW - NMR

KW - CYCLOHEXENE

KW - HETEROPOLYMETALATE CLUSTERS

KW - POLYOXOMETALATE

UR - http://www.scopus.com/inward/record.url?scp=85060220559&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2018.12.047

DO - 10.1016/j.poly.2018.12.047

M3 - Article

AN - SCOPUS:85060220559

VL - 161

SP - 78

EP - 83

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

ER -

Mixed [{β-B-SbM9O33}2(µ-MO2)2]14− (M = W, Mo) polyoxoanions

Аннотация

Доступ к документу

Цитировать

Mixed [{β-B-SbM₉O₃₃}₂(µ-MO₂)₂]¹⁴⁻ (M = W, Mo) polyoxoanions