@article{e4b965b9406740929a2becee4be7993b,
title = "Mixed [{β-B-SbM9O33}2(µ-MO2)2]14− (M = W, Mo) polyoxoanions",
abstract = "The reaction of Na9[α-B-SbW9O33]·19.5H2O with Na2MoO4 results in the formation of new mixed W/Mo polyanions, isolated as various salts, (Me2NH2)11Na[Sb2Mo4W16O70(MoO2)]·17H2O (1a) and (Me4N)6Na5[Sb2Mo3.5W16.5O70(MoO2)1.5]·27H2O (2). Both 1a and 2 were characterized by XRD, XRPD, IR, Raman spectra and elemental analysis. According to HPLC-ICP-AES, both 1a and 2 equilibrate in aqueous solutions with the constituent {SbM9} anions.",
keywords = "Mixed W/Mo polyoxoanions, Raman spectroscopy, Solution behavior, Structural changes, XRD, OXIDATION, COMPLEXES, STRUCTURAL-CHARACTERIZATION, CRYSTAL-STRUCTURES, IDENTIFICATION, FAMILY, NMR, CYCLOHEXENE, HETEROPOLYMETALATE CLUSTERS, POLYOXOMETALATE",
author = "Shmakova, {Alexandra A.} and Volchek, {Victoria V.} and Shiriyazdanov, {Rishat R.} and Karimova, {Albina R.} and Abramov, {Pavel A.} and Sokolov, {Maxim N.}",
year = "2019",
month = mar,
day = "15",
doi = "10.1016/j.poly.2018.12.047",
language = "English",
volume = "161",
pages = "78--83",
journal = "Polyhedron",
issn = "0277-5387",
publisher = "Elsevier",
}