TY - JOUR
T1 - Methane photo-acoustic gas analyzer based on 7.7-μm quantum cascade laser
AU - Sherstov, I. V.
AU - Kolker, D. B.
AU - Boyko, A. A.
AU - Vasiliev, V. A.
AU - Pustovalova, R. V.
N1 - Funding Information:
The authors are sincerely grateful to A.V. Pavlyuk, N.Yu. Kostyukova, E.Yu. Erushin (all - Novosibirsk State University, Novosibirsk) for the assistance in the experiments. The work was carried out within the framework of the project of the National Technological Initiative ?Development and creation of a breakthrough complex for geophysical exploration using UAV? (?Aerotomography?), and also partially with the financial support of the Russian Science Foundation grant 17-72-30006.
Funding Information:
The work was carried out within the framework of the project of the National Technological Initiative “Development and creation of a breakthrough complex for geophysical exploration using UAV” (“Aerotomography”), and also partially with the financial support of the Russian Science Foundation grant 17-72-30006 .
Publisher Copyright:
© 2021 Elsevier B.V.
Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/9
Y1 - 2021/9
N2 - The photo-acoustic (PA) methane gas analyzer based on a quantum cascade laser (QCL; ~7.7 μm/1800 Hz/24 mW), a resonant differential PA detector, and a sealed gas-filled cell was investigated. The measurement of methane concentration below the background value in the air (~0.3 ppm CH4) is shown, the standard dispersion was (1σ) ≈ (10–11) ppb CH4 with an integration time of 10 s. Under conditions of temperature instability (or emission wavelength) of QCL when normalized to a gas-filled cell, the relative measurement error of the CH4 concentration does not exceed 3%. A decrease in the average QCL radiation power (~24–12–6 mW) leads to a noticeable deterioration in the threshold sensitivity of the PA gas analyzer. It is recommended to increase the average QCL power level to ~50 mW. The dynamic range of measuring the concentration of methane of the PA gas analyzer in the linear mode was ~4 decades (from 0.3 ppm to 2000–3000 ppm CH4).
AB - The photo-acoustic (PA) methane gas analyzer based on a quantum cascade laser (QCL; ~7.7 μm/1800 Hz/24 mW), a resonant differential PA detector, and a sealed gas-filled cell was investigated. The measurement of methane concentration below the background value in the air (~0.3 ppm CH4) is shown, the standard dispersion was (1σ) ≈ (10–11) ppb CH4 with an integration time of 10 s. Under conditions of temperature instability (or emission wavelength) of QCL when normalized to a gas-filled cell, the relative measurement error of the CH4 concentration does not exceed 3%. A decrease in the average QCL radiation power (~24–12–6 mW) leads to a noticeable deterioration in the threshold sensitivity of the PA gas analyzer. It is recommended to increase the average QCL power level to ~50 mW. The dynamic range of measuring the concentration of methane of the PA gas analyzer in the linear mode was ~4 decades (from 0.3 ppm to 2000–3000 ppm CH4).
KW - Methane
KW - Photo-acoustic gas analyzer
KW - Quantum-cascade laser
KW - Resonant differential photo-acoustic detector
UR - http://www.scopus.com/inward/record.url?scp=85111895099&partnerID=8YFLogxK
UR - https://elibrary.ru/item.asp?id=46996190
U2 - 10.1016/j.infrared.2021.103858
DO - 10.1016/j.infrared.2021.103858
M3 - Article
AN - SCOPUS:85111895099
VL - 117
JO - Infrared Physics and Technology
JF - Infrared Physics and Technology
SN - 1350-4495
M1 - 103858
ER -