Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers

Y. M. Litvinova; Y. M. Gayfulin; D. G. Samsonenko; Y. V. Mironov

doi:10.1007/s11172-020-2896-2

Metal-organic frameworks based on [Re₆Se₈(CN)₆]⁴⁻ cluster anions, Yb³⁺ cations, and thiophene-2,5-dicarboxylate linkers

Y. M. Litvinova, Y. M. Gayfulin, D. G. Samsonenko, Y. V. Mironov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

The reaction of [Re₆Se₈(CN)₆]⁴⁻ cluster anions with Ln³⁺ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H₂O)₃}₂(tdc)-Re₆Se₈(CN)₆]•10H₂O (1) and CsK_0,5[{Yb₄(OH)₄(H₂O)_7,5(NO₃)_0,5(tdc)₂}{Re₆Se₈(CN)₆}]NO₃ • 16.5H₂O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb₄(OH)₄]⁸⁺, and also has a framework structure.

Язык оригинала	английский
Страницы (с-по)	1264-1271
Число страниц	8
Журнал	Russian Chemical Bulletin
Том	69
Номер выпуска	7
DOI	https://doi.org/10.1007/s11172-020-2896-2
Состояние	Опубликовано - 1 июл. 2020

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10.1007/s11172-020-2896-2

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title = "Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers",

abstract = "The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.",

keywords = "cluster complex, crystal structure, lanthanides, metal-organic frameworks, rhenium, CONVERSION, COMPLEXES, CRYSTAL-STRUCTURES, NANOPARTICLES, LUMINESCENT, LANTHANIDE, COORDINATION POLYMERS, CLUSTER",

author = "Litvinova, {Y. M.} and Gayfulin, {Y. M.} and Samsonenko, {D. G.} and Mironov, {Y. V.}",

year = "2020",

month = jul,

day = "1",

doi = "10.1007/s11172-020-2896-2",

language = "English",

volume = "69",

pages = "1264--1271",

journal = "Russian Chemical Bulletin",

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number = "7",

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Metal-organic frameworks based on [Re₆Se₈(CN)₆]⁴⁻ cluster anions, Yb³⁺ cations, and thiophene-2,5-dicarboxylate linkers. / Litvinova, Y. M.; Gayfulin, Y. M.; Samsonenko, D. G. и др.

В: Russian Chemical Bulletin, Том 69, № 7, 01.07.2020, стр. 1264-1271.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Metal-organic frameworks based on [Re6Se8(CN)6]4− cluster anions, Yb3+ cations, and thiophene-2,5-dicarboxylate linkers

AU - Litvinova, Y. M.

AU - Gayfulin, Y. M.

AU - Samsonenko, D. G.

AU - Mironov, Y. V.

PY - 2020/7/1

Y1 - 2020/7/1

N2 - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.

AB - The reaction of [Re6Se8(CN)6]4− cluster anions with Ln3+ cations in the presence of thiophene-2,5-dicarboxylate anions in an aqueous solution was studied. Two new framework compounds were synthesized and structurally characterized: [{Yb(H2O)3}2(tdc)-Re6Se8(CN)6]•10H2O (1) and CsK0,5[{Yb4(OH)4(H2O)7,5(NO3)0,5(tdc)2}{Re6Se8(CN)6}]NO3 • 16.5H2O (2) (tdc is the thiophene-2,5-dicarboxylate anion). Compound 1 crystallizes in a wide pH range (3.0–6.5) and has a porous structure with large open voids accessible to guest molecules. Compound 2 crystallizes at pH 6.0–6.5, contains polynuclear cationic complexes [Yb4(OH)4]8+, and also has a framework structure.

KW - cluster complex

KW - crystal structure

KW - lanthanides

KW - metal-organic frameworks

KW - rhenium

KW - CONVERSION

KW - COMPLEXES

KW - CRYSTAL-STRUCTURES

KW - NANOPARTICLES

KW - LUMINESCENT

KW - LANTHANIDE

KW - COORDINATION POLYMERS

KW - CLUSTER

UR - http://www.scopus.com/inward/record.url?scp=85090147801&partnerID=8YFLogxK

U2 - 10.1007/s11172-020-2896-2

DO - 10.1007/s11172-020-2896-2

M3 - Article

AN - SCOPUS:85090147801

VL - 69

SP - 1264

EP - 1271

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 7

ER -