TY - JOUR
T1 - Metal-organic frameworks based on 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane
T2 - synthesis, structure, and properties
AU - Lysova, A. A.
AU - Marchenko, R. D.
AU - Samsonenko, D. G.
AU - Potapov, A. S.
AU - Fedin, V. P.
PY - 2020/6/1
Y1 - 2020/6/1
N2 - Four new metal-organic frameworks were synthesized based on the N-donor ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane (L) novel in this field of chemistry: three one-dimensional metal-organic frameworks based on silver(I) cations, [Ag3(L)2(NO3)2]-NO3·MeOH (1), [Ag(L)]NO3 (2), and [Ag(L)(H2O)]NO3 (3), and one three-dimensional metal-organic framework [Zn3(bdc)3(L)]·0.5 MeOH (4, H2bdc is 1,4-benzenedicarboxylic acid). Compounds 1 and 4 contain trinuclear units. In compound 1, these units are linked via the ligand L to form polymer chains. In compound 4, the ligand L bridges polymer layers, which are composed of carboxylate units {Zn3(bdc)6}, to form a three-dimensional framework. Compounds 2 and 3 are composed of mononuclear units, which are connected via the ligand L to form polymer chains. Luminescence of compound 3 was found to be due to intraligand transitions.
AB - Four new metal-organic frameworks were synthesized based on the N-donor ligand 1,5-bis(3,5-dimethylpyrazol-1-yl)-3-selenapentane (L) novel in this field of chemistry: three one-dimensional metal-organic frameworks based on silver(I) cations, [Ag3(L)2(NO3)2]-NO3·MeOH (1), [Ag(L)]NO3 (2), and [Ag(L)(H2O)]NO3 (3), and one three-dimensional metal-organic framework [Zn3(bdc)3(L)]·0.5 MeOH (4, H2bdc is 1,4-benzenedicarboxylic acid). Compounds 1 and 4 contain trinuclear units. In compound 1, these units are linked via the ligand L to form polymer chains. In compound 4, the ligand L bridges polymer layers, which are composed of carboxylate units {Zn3(bdc)6}, to form a three-dimensional framework. Compounds 2 and 3 are composed of mononuclear units, which are connected via the ligand L to form polymer chains. Luminescence of compound 3 was found to be due to intraligand transitions.
KW - 1,5-bis(3,5-dimethyl-pyrazol-1-yl)-3-selenapentane
KW - metal-organic frameworks
KW - silver
KW - X-ray diffraction
KW - zinc
KW - 1
KW - 5-dimethyl-pyrazol-1-yl)-3-selenapentane
KW - 5-bis(3
UR - http://www.scopus.com/inward/record.url?scp=85088239476&partnerID=8YFLogxK
U2 - 10.1007/s11172-020-2877-5
DO - 10.1007/s11172-020-2877-5
M3 - Article
AN - SCOPUS:85088239476
VL - 69
SP - 1122
EP - 1129
JO - Russian Chemical Bulletin
JF - Russian Chemical Bulletin
SN - 1066-5285
IS - 6
ER -