Metal-metal bond excitation in colloidal solution of NbS3

Sofya B. Artemkina; Ekaterina D. Grayfer; Mariia N. Kozlova; Svetlana G. Kozlova; Maxim R. Ryzhikov; Igor R. Shein; Vladimir E. Fedorov

doi:10.1016/j.saa.2017.02.005

Metal-metal bond excitation in colloidal solution of NbS₃

Sofya B. Artemkina, Ekaterina D. Grayfer, Mariia N. Kozlova, Svetlana G. Kozlova, Maxim R. Ryzhikov, Igor R. Shein, Vladimir E. Fedorov

Результат исследования: Научные публикации в периодических изданиях › статья

2 Цитирования (Scopus)

Аннотация

For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS₃ can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

Язык оригинала	английский
Страницы (с-по)	46-50
Число страниц	5
Журнал	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Том	179
DOI	https://doi.org/10.1016/j.saa.2017.02.005
Состояние	Опубликовано - 15 мая 2017

Доступ к документу

10.1016/j.saa.2017.02.005

Link to publication in Scopus

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Цитировать

Artemkina, S. B., Grayfer, E. D., Kozlova, M. N., Kozlova, S. G., Ryzhikov, M. R., Shein, I. R., & Fedorov, V. E. (2017). Metal-metal bond excitation in colloidal solution of NbS₃. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 179, 46-50. https://doi.org/10.1016/j.saa.2017.02.005

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title = "Metal-metal bond excitation in colloidal solution of NbS3",

abstract = "For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.",

keywords = "Band calculations, DFT, NbS colloidal dispersion, UV–vis spectra, GRAPHENE OXIDE, UV-vis spectra, NIOBIUM TRISULFIDE, OPTICAL-PROPERTIES, GENERALIZED GRADIENT APPROXIMATION, LAYERS, TRANSITION, DIMENSIONAL CONDUCTOR NBS3, NbS3 colloidal dispersion, ELECTRONIC-STRUCTURE",

author = "Artemkina, {Sofya B.} and Grayfer, {Ekaterina D.} and Kozlova, {Mariia N.} and Kozlova, {Svetlana G.} and Ryzhikov, {Maxim R.} and Shein, {Igor R.} and Fedorov, {Vladimir E.}",

year = "2017",

month = may,

day = "15",

doi = "10.1016/j.saa.2017.02.005",

language = "English",

volume = "179",

pages = "46--50",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier",

}

Metal-metal bond excitation in colloidal solution of NbS₃. / Artemkina, Sofya B.; Grayfer, Ekaterina D.; Kozlova, Mariia N.; Kozlova, Svetlana G.; Ryzhikov, Maxim R.; Shein, Igor R.; Fedorov, Vladimir E.

В: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Том 179, 15.05.2017, стр. 46-50.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Metal-metal bond excitation in colloidal solution of NbS3

AU - Artemkina, Sofya B.

AU - Grayfer, Ekaterina D.

AU - Kozlova, Mariia N.

AU - Kozlova, Svetlana G.

AU - Ryzhikov, Maxim R.

AU - Shein, Igor R.

AU - Fedorov, Vladimir E.

PY - 2017/5/15

Y1 - 2017/5/15

N2 - For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

AB - For the first time the comparison of the theoretical and experimental data have shown that UV–vis absorption in the region of 600 nm in colloidal solution of NbS3 can be described by the d-d electronic transitions to the antibonding molecular orbital. It is proved that the process leads to excitation of metal-metal bond.

KW - Band calculations

KW - DFT

KW - NbS colloidal dispersion

KW - UV–vis spectra

KW - GRAPHENE OXIDE

KW - UV-vis spectra

KW - NIOBIUM TRISULFIDE

KW - OPTICAL-PROPERTIES

KW - GENERALIZED GRADIENT APPROXIMATION

KW - LAYERS

KW - TRANSITION

KW - DIMENSIONAL CONDUCTOR NBS3

KW - NbS3 colloidal dispersion

KW - ELECTRONIC-STRUCTURE

UR - http://www.scopus.com/inward/record.url?scp=85013071197&partnerID=8YFLogxK

U2 - 10.1016/j.saa.2017.02.005

DO - 10.1016/j.saa.2017.02.005

M3 - Article

C2 - 28214428

AN - SCOPUS:85013071197

VL - 179

SP - 46

EP - 50

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

SN - 1386-1425

ER -