Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions

Anton A. Shushakov; Svetlana G. Matveeva; Ivan P. Pozdnyakov; Vjacheslav P. Grivin; Victor F. Plyusnin; Danila B. Vasilchenko; Alexei A. Melnikov; Sergei V. Chekalin; Evgeni M. Glebov

doi:10.1039/d0pp00178c

Mechanistic study of thetrans,cis,cis-[RuCl₂(DMSO)₂(H₂O)₂] complex photochemistry in aqueous solutions

Anton A. Shushakov, Svetlana G. Matveeva, Ivan P. Pozdnyakov, Vjacheslav P. Grivin, Victor F. Plyusnin, Danila B. Vasilchenko, Alexei A. Melnikov, Sergei V. Chekalin, Evgeni M. Glebov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

It is known thattrans,cis,cis-[RuCl₂(DMSO)₂(H₂O)₂] (1a) complexes, which are formed upon dissolution oftrans-[RuCl₂(DMSO)₄] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.

Язык оригинала	английский
Страницы (с-по)	1222-1229
Число страниц	8
Журнал	Photochemical and Photobiological Sciences
Том	19
Номер выпуска	9
DOI	https://doi.org/10.1039/d0pp00178c
Состояние	Опубликовано - сен 2020

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10.1039/d0pp00178c

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Shushakov, Anton A. ; Matveeva, Svetlana G. ; Pozdnyakov, Ivan P. ; Grivin, Vjacheslav P. ; Plyusnin, Victor F. ; Vasilchenko, Danila B. ; Melnikov, Alexei A. ; Chekalin, Sergei V. ; Glebov, Evgeni M. / Mechanistic study of thetrans,cis,cis-[RuCl₂(DMSO)₂(H₂O)₂] complex photochemistry in aqueous solutions. В: Photochemical and Photobiological Sciences. 2020 ; Том 19, № 9. стр. 1222-1229.

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title = "Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions",

abstract = "It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.",

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author = "Shushakov, {Anton A.} and Matveeva, {Svetlana G.} and Pozdnyakov, {Ivan P.} and Grivin, {Vjacheslav P.} and Plyusnin, {Victor F.} and Vasilchenko, {Danila B.} and Melnikov, {Alexei A.} and Chekalin, {Sergei V.} and Glebov, {Evgeni M.}",

year = "2020",

month = sep,

doi = "10.1039/d0pp00178c",

language = "English",

volume = "19",

pages = "1222--1229",

journal = "Photochemical and Photobiological Sciences",

issn = "1474-905X",

publisher = "Royal Society of Chemistry",

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Mechanistic study of thetrans,cis,cis-[RuCl₂(DMSO)₂(H₂O)₂] complex photochemistry in aqueous solutions. / Shushakov, Anton A.; Matveeva, Svetlana G.; Pozdnyakov, Ivan P.; Grivin, Vjacheslav P.; Plyusnin, Victor F.; Vasilchenko, Danila B.; Melnikov, Alexei A.; Chekalin, Sergei V.; Glebov, Evgeni M.

В: Photochemical and Photobiological Sciences, Том 19, № 9, 09.2020, стр. 1222-1229.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Mechanistic study of thetrans,cis,cis-[RuCl2(DMSO)2(H2O)2] complex photochemistry in aqueous solutions

AU - Shushakov, Anton A.

AU - Matveeva, Svetlana G.

AU - Pozdnyakov, Ivan P.

AU - Grivin, Vjacheslav P.

AU - Plyusnin, Victor F.

AU - Vasilchenko, Danila B.

AU - Melnikov, Alexei A.

AU - Chekalin, Sergei V.

AU - Glebov, Evgeni M.

PY - 2020/9

Y1 - 2020/9

N2 - It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.

AB - It is known thattrans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution oftrans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of1aphotochemistry has been performed using ultrafast pump-probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of1aphotochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating by values 0.3 and 0.04 upon irradiation at 308 and 430 nm, respectively). The mechanism of photoexchange is complicated involving at least four Ru(ii) intermediates. Two tentative mechanisms of the process are proposed.

KW - RUTHENIUM(III)

KW - PHOTOPHYSICS

KW - FE(III)

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DO - 10.1039/d0pp00178c

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JO - Photochemical and Photobiological Sciences

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SN - 1474-905X

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