Mapping Magnetic Properties and Relaxation in Vanadium(IV) Complexes with Lanthanides by Electron Paramagnetic Resonance

Ivan V. Kurganskii, Evgeniya S. Bazhina, Alexander A. Korlyukov, Konstantin A. Babeshkin, Nikolay N. Efimov, Mikhail A. Kiskin, Sergey L. Veber, Alexey A. Sidorov, Igor L. Eremenko, Matvey V. Fedin

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

Vanadium(IV) complexes are actively studied as potential candidates for molecular spin qubits operating at room temperatures. They have longer electron spin decoherence times than many other transition ions, being the key property for applications in quantum information processing. In most cases reported to date, the molecular complexes were optimized through the design for this purpose. In this work, we investigate the relaxation properties of vanadium(IV) ions incorporated in complexes with lanthanides using electron paramagnetic resonance (EPR). In all cases, the VO6 moieties with no nuclear spins in the first coordination sphere are addressed. We develop and implement the approaches for facile diagnostics of relaxation characteristics in individual VO6 moieties of such compounds. Remarkably, the estimated relaxation times are found to be close to those of other vanadium-based qubits obtained previously. In the future, a synergistic combination of qubit-friendly properties of vanadium ions with single-molecule magnetism and luminescence of lanthanides can be pursued to realize new functionalities of such materials.

Язык оригиналаанглийский
Номер статьи4582
Число страниц12
ЖурналMolecules (Basel, Switzerland)
Том24
Номер выпуска24
DOI
СостояниеОпубликовано - 14 дек 2019

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