Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex

Katerina A. Vinogradova; Denis P. Pishchur; Ilya V. Korolkov; Mark B. Bushuev

doi:10.1016/j.inoche.2019.04.035

Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex

Katerina A. Vinogradova, Denis P. Pishchur, Ilya V. Korolkov, Mark B. Bushuev

Кафедра аналитической химии ФЕН

Результат исследования: Научные публикации в периодических изданиях › статья

4 Цитирования (Scopus)

Аннотация

A polymeric iron(II) complex, Fe(ATrz) ₃ (NO ₃ ) ₂ ·nH ₂ O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH ₃ , HNO ₃ and HBr vapors.

Язык оригинала	английский
Страницы (с-по)	82-85
Число страниц	4
Журнал	Inorganic Chemistry Communications
Том	105
DOI	https://doi.org/10.1016/j.inoche.2019.04.035
Состояние	Опубликовано - 1 июл 2019

Доступ к документу

10.1016/j.inoche.2019.04.035

Link to publication in Scopus

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Цитировать

Vinogradova, K. A., Pishchur, D. P., Korolkov, I. V., & Bushuev, M. B. (2019). Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex. Inorganic Chemistry Communications, 105, 82-85. https://doi.org/10.1016/j.inoche.2019.04.035

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abstract = " A polymeric iron(II) complex, Fe(ATrz) 3 (NO 3 ) 2 ·nH 2 O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH 3 , HNO 3 and HBr vapors. ",

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Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex. / Vinogradova, Katerina A.; Pishchur, Denis P.; Korolkov, Ilya V.; Bushuev, Mark B.

В: Inorganic Chemistry Communications, Том 105, 01.07.2019, стр. 82-85.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex

AU - Vinogradova, Katerina A.

AU - Pishchur, Denis P.

AU - Korolkov, Ilya V.

AU - Bushuev, Mark B.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - A polymeric iron(II) complex, Fe(ATrz) 3 (NO 3 ) 2 ·nH 2 O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH 3 , HNO 3 and HBr vapors.

AB - A polymeric iron(II) complex, Fe(ATrz) 3 (NO 3 ) 2 ·nH 2 O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH 3 , HNO 3 and HBr vapors.

KW - TRANSITION

KW - POLYMERS

KW - FILMS

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EP - 85

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

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