TY - JOUR
T1 - Magnetic properties and vapochromism of a composite on the base of an iron(II) spin crossover complex
AU - Vinogradova, Katerina A.
AU - Pishchur, Denis P.
AU - Korolkov, Ilya V.
AU - Bushuev, Mark B.
PY - 2019/7/1
Y1 - 2019/7/1
N2 -
A polymeric iron(II) complex, Fe(ATrz)
3
(NO
3
)
2
·nH
2
O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH
3
, HNO
3
and HBr vapors.
AB -
A polymeric iron(II) complex, Fe(ATrz)
3
(NO
3
)
2
·nH
2
O (ATrz = 4-amino-1,2,4-triazole), can be embedded in the polystyrene matrix to form a composite spin crossover material. This composite material can be prepared in the form of films with a thickness of ca. 10–20 μm. The material demonstrates two spin crossover regimes (with and without thermal hysteresis) and reversible switching between these regimes, thermochromic effect (pink – white) and vapochromic behavior in the atmosphere of HCl, NH
3
, HNO
3
and HBr vapors.
KW - TRANSITION
KW - POLYMERS
KW - FILMS
KW - WATER
UR - http://www.scopus.com/inward/record.url?scp=85065069335&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2019.04.035
DO - 10.1016/j.inoche.2019.04.035
M3 - Article
AN - SCOPUS:85065069335
VL - 105
SP - 82
EP - 85
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -