Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies

Darya V. Evtushok; Natalya A. Vorotnikova; Vladimir A. Logvinenko; Anton I. Smolentsev; Konstantin A. Brylev; Pavel E. Plyusnin; Denis P. Pishchur; Noboru Kitamura; Yuri V. Mironov; Anastasiya O. Solovieva; Olga A. Efremova; Michael A. Shestopalov

doi:10.1039/c7nj02858j

Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ ₈}Cl^a ₆]^2- (M = Mo, W): Synthesis and thermal stability studies

Darya V. Evtushok, Natalya A. Vorotnikova, Vladimir A. Logvinenko, Anton I. Smolentsev, Konstantin A. Brylev, Pavel E. Plyusnin, Denis P. Pishchur, Noboru Kitamura, Yuri V. Mironov, Anastasiya O. Solovieva, Olga A. Efremova, Michael A. Shestopalov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

9 Цитирования (Scopus)

Аннотация

Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh₃)₄}{{M₆Clⁱ ₈}Cl^a ₆}]_∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh₃)₄(H₂O)₂][{M₆Clⁱ ₈}Cl^a ₆]·2CH₃CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.

Язык оригинала	английский
Страницы (с-по)	14855-14861
Число страниц	7
Журнал	New Journal of Chemistry
Том	41
Номер выпуска	24
DOI	https://doi.org/10.1039/c7nj02858j
Состояние	Опубликовано - 21 дек 2017

Доступ к документу

10.1039/c7nj02858j

Link to publication in Scopus

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Цитировать

Evtushok, D. V., Vorotnikova, N. A., Logvinenko, V. A., Smolentsev, A. I., Brylev, K. A., Plyusnin, P. E., Pishchur, D. P., Kitamura, N., Mironov, Y. V., Solovieva, A. O., Efremova, O. A., & Shestopalov, M. A. (2017). Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ ₈}Cl^a ₆]^2- (M = Mo, W): Synthesis and thermal stability studies. New Journal of Chemistry, 41(24), 14855-14861. https://doi.org/10.1039/c7nj02858j

Evtushok, Darya V. ; Vorotnikova, Natalya A. ; Logvinenko, Vladimir A. ; Smolentsev, Anton I. ; Brylev, Konstantin A. ; Plyusnin, Pavel E. ; Pishchur, Denis P. ; Kitamura, Noboru ; Mironov, Yuri V. ; Solovieva, Anastasiya O. ; Efremova, Olga A. ; Shestopalov, Michael A. / Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ ₈}Cl^a ₆]^2- (M = Mo, W) : Synthesis and thermal stability studies. В: New Journal of Chemistry. 2017 ; Том 41, № 24. стр. 14855-14861.

@article{7251ee7aed794936a715e18e025f8a3b,

title = "Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W): Synthesis and thermal stability studies",

abstract = "Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.",

keywords = "CRYSTAL-STRUCTURE, HEXANUCLEAR MOLYBDENUM, BUILDING-BLOCKS, COMPLEXES, METHANOL, COMPOUND, CHLORIDE, LIGANDS, CALCIUM, CATIONS",

author = "Evtushok, {Darya V.} and Vorotnikova, {Natalya A.} and Logvinenko, {Vladimir A.} and Smolentsev, {Anton I.} and Brylev, {Konstantin A.} and Plyusnin, {Pavel E.} and Pishchur, {Denis P.} and Noboru Kitamura and Mironov, {Yuri V.} and Solovieva, {Anastasiya O.} and Efremova, {Olga A.} and Shestopalov, {Michael A.}",

year = "2017",

month = dec,

day = "21",

doi = "10.1039/c7nj02858j",

language = "English",

volume = "41",

pages = "14855--14861",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "24",

}

Evtushok, DV, Vorotnikova, NA, Logvinenko, VA, Smolentsev, AI, Brylev, KA , Plyusnin, PE, Pishchur, DP, Kitamura, N, Mironov, YV, Solovieva, AO, Efremova, OA & Shestopalov, MA 2017, 'Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ ₈}Cl^a ₆]^2- (M = Mo, W): Synthesis and thermal stability studies', New Journal of Chemistry, том. 41, № 24, стр. 14855-14861. https://doi.org/10.1039/c7nj02858j

Luminescent coordination polymers based on Ca²⁺ and octahedral cluster anions [{M₆Clⁱ ₈}Cl^a ₆]^2- (M = Mo, W) : Synthesis and thermal stability studies. / Evtushok, Darya V.; Vorotnikova, Natalya A.; Logvinenko, Vladimir A.; Smolentsev, Anton I.; Brylev, Konstantin A.; Plyusnin, Pavel E.; Pishchur, Denis P.; Kitamura, Noboru; Mironov, Yuri V.; Solovieva, Anastasiya O.; Efremova, Olga A.; Shestopalov, Michael A.

В: New Journal of Chemistry, Том 41, № 24, 21.12.2017, стр. 14855-14861.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Luminescent coordination polymers based on Ca2+ and octahedral cluster anions [{M6Cli 8}Cla 6]2- (M = Mo, W)

T2 - Synthesis and thermal stability studies

AU - Evtushok, Darya V.

AU - Vorotnikova, Natalya A.

AU - Logvinenko, Vladimir A.

AU - Smolentsev, Anton I.

AU - Brylev, Konstantin A.

AU - Plyusnin, Pavel E.

AU - Pishchur, Denis P.

AU - Kitamura, Noboru

AU - Mironov, Yuri V.

AU - Solovieva, Anastasiya O.

AU - Efremova, Olga A.

AU - Shestopalov, Michael A.

PY - 2017/12/21

Y1 - 2017/12/21

N2 - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.

AB - Luminescent coordination polymers (CPs) based on inexpensive stable precursors are attractive materials for applications. Here we report the synthesis and evaluation of the stability and photophysical characteristics of the first examples of phosphorescent CPs based on octahedral molybdenum and tungsten cluster anions. In particular, 1D CP trans-[{Ca(OPPh3)4}{{M6Cli 8}Cla 6}]∞ (M = Mo, W) can be obtained either directly at increased temperature or via intermediate phases [cis-Ca(OPPh3)4(H2O)2][{M6Cli 8}Cla 6]·2CH3CN that are stable at room-temperature, but convert to the titled CPs at temperatures above 100 °C.

KW - CRYSTAL-STRUCTURE

KW - HEXANUCLEAR MOLYBDENUM

KW - BUILDING-BLOCKS

KW - COMPLEXES

KW - METHANOL

KW - COMPOUND

KW - CHLORIDE

KW - LIGANDS

KW - CALCIUM

KW - CATIONS

UR - http://www.scopus.com/inward/record.url?scp=85037651360&partnerID=8YFLogxK

U2 - 10.1039/c7nj02858j

DO - 10.1039/c7nj02858j

M3 - Article

AN - SCOPUS:85037651360

VL - 41

SP - 14855

EP - 14861

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

IS - 24

ER -