Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply

S. D. Badmaev; N. O. Akhmetov; A. A. Pechenkin; V. A. Sobyanin; V. N. Parmon

doi:10.1134/S0012501619080013

Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO₂/γ-Al₂O₃ Catalysts for Fuel Cell Supply

S. D. Badmaev, N. O. Akhmetov, A. A. Pechenkin, V. A. Sobyanin, V. N. Parmon

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Abstract: The CuO–CeO₂/γ-Al₂O₃ systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(g_cat h) and the DME : O₂ : N₂ molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH₄ (≤0.8 mol %) and H₂ production rate of ~3.1 L/(g_cat h).

Язык оригинала	английский
Страницы (с-по)	95-98
Число страниц	4
Журнал	Doklady Physical Chemistry
Том	487
Номер выпуска	2
DOI	https://doi.org/10.1134/S0012501619080013
Состояние	Опубликовано - 1 авг 2019

Предметные области OECD FOS+WOS

1.04 ХИМИЧЕСКИЕ НАУКИ

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10.1134/S0012501619080013

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title = "Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply",

abstract = "Abstract: The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).",

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Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO₂/γ-Al₂O₃ Catalysts for Fuel Cell Supply. / Badmaev, S. D.; Akhmetov, N. O.; Pechenkin, A. A.; Sobyanin, V. A.; Parmon, V. N.

В: Doklady Physical Chemistry, Том 487, № 2, 01.08.2019, стр. 95-98.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Low-Temperature Partial Oxidation of Dimethyl Ether to Hydrogen-Rich Gas over CuO–CeO2/γ-Al2O3 Catalysts for Fuel Cell Supply

AU - Badmaev, S. D.

AU - Akhmetov, N. O.

AU - Pechenkin, A. A.

AU - Sobyanin, V. A.

AU - Parmon, V. N.

PY - 2019/8/1

Y1 - 2019/8/1

N2 - Abstract: The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).

AB - Abstract: The CuO–CeO2/γ-Al2O3 systems have good prospects as catalysts for partial oxidation of dimethyl ether (DME) with air to give hydrogen-rich gas for fuel cell feeding. At atmospheric pressure, temperature of ~350°C, and reaction mixture flow rate of 7 L/(gcat h) and the DME : O2 : N2 molar ratio of 1 : 1 : 4 (DME : air = 1 : 5), the catalysts provide complete DME conversion to hydrogen-rich gas with a low content of CH4 (≤0.8 mol %) and H2 production rate of ~3.1 L/(gcat h).

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JO - Doklady Physical Chemistry

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