Lanthanum complex with mono- and dideprotonated diketoimine

P. A. Petrov; I. V. El’tsov

doi:10.1134/S1070328417090068

Lanthanum complex with mono- and dideprotonated diketoimine

P. A. Petrov, I. V. El’tsov

Результат исследования: Научные публикации в периодических изданиях › статья

1 Цитирования (Scopus)

Аннотация

The reaction of LaCl₃ with ß-diketoimine potassium salt K^Dipp,MeNacnac (KL) affords the molecular complex [LaLL'] with singly and doubly deprotonated diketoimine. The complex is characterized by single- crystal X-ray diffraction analysis (CIF file CCDC 1528658). The structure of [LaLL'] in solution is studied by 1D and 2D ¹H and ¹³C NMR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	600-603
Число страниц	4
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	43
Номер выпуска	9
DOI	https://doi.org/10.1134/S1070328417090068
Состояние	Опубликовано - 1 сен 2017

Доступ к документу

10.1134/S1070328417090068

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title = "Lanthanum complex with mono- and dideprotonated diketoimine",

abstract = "The reaction of LaCl3 with {\ss}-diketoimine potassium salt KDipp,MeNacnac (KL) affords the molecular complex [LaLL'] with singly and doubly deprotonated diketoimine. The complex is characterized by single- crystal X-ray diffraction analysis (CIF file CCDC 1528658). The structure of [LaLL'] in solution is studied by 1D and 2D 1H and 13C NMR spectroscopy.",

keywords = "diketoimines, lanthanum, NMR spectroscopy, rare-earth elements, X-ray diffraction analysis, DEPROTONATION, REACTIVITY, CHEMISTRY, COORDINATION, LIGAND",

author = "Petrov, {P. A.} and El{\textquoteright}tsov, {I. V.}",

year = "2017",

month = sep,

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AU - El’tsov, I. V.

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N2 - The reaction of LaCl3 with ß-diketoimine potassium salt KDipp,MeNacnac (KL) affords the molecular complex [LaLL'] with singly and doubly deprotonated diketoimine. The complex is characterized by single- crystal X-ray diffraction analysis (CIF file CCDC 1528658). The structure of [LaLL'] in solution is studied by 1D and 2D 1H and 13C NMR spectroscopy.

AB - The reaction of LaCl3 with ß-diketoimine potassium salt KDipp,MeNacnac (KL) affords the molecular complex [LaLL'] with singly and doubly deprotonated diketoimine. The complex is characterized by single- crystal X-ray diffraction analysis (CIF file CCDC 1528658). The structure of [LaLL'] in solution is studied by 1D and 2D 1H and 13C NMR spectroscopy.

KW - diketoimines

KW - lanthanum

KW - NMR spectroscopy

KW - rare-earth elements

KW - X-ray diffraction analysis

KW - DEPROTONATION

KW - REACTIVITY

KW - CHEMISTRY

KW - COORDINATION

KW - LIGAND

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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