L-Cysteine picrates

V. V. Ghazaryan, T. N. Drebushchak, R. A. Apreyan, E. V. Boldyreva, A. M. Petrosyan

Результат исследования: Научные публикации в периодических изданияхстатьярецензирование

2 Цитирования (Scopus)


Two picrates of l-cysteine have been obtained, (l-CysH)picrate (I) and l-Cys(l-Cys-½H···½H- l-Cys)picrate (II). The (I) crystallizes in the monoclinic space group P21 and the (II) in the orthorhombic space group P212121. (l-CysH)picrate (I) is a simple salt with l-cysteinium cation, while l-Cys(l-Cys-½H···½H- l-Cys)picrate (II) includes (l-Cys-½H···½H- l-Cys) dimeric cation formed by O–H⋯O hydrogen bonds with O⋯O distance of 2.442(11) Å. Also, there is a l-cysteine zwitterion in the structure. Infrared and Raman spectra were registered. They are discussed in relation to the characteristics of the hydrogen bonds. l-Cysteinium picrate (I) has nonlinear-optical properties. The intensity of second harmonic generation signal is 1.6 times higher than that of KDP.

Язык оригиналаанглийский
Номер статьи127788
Число страниц7
ЖурналJournal of Molecular Structure
СостояниеОпубликовано - 5 мая 2020


Подробные сведения о темах исследования «L-Cysteine picrates». Вместе они формируют уникальный семантический отпечаток (fingerprint).