Isostructurality and Thermal Properties in the Series of Double Complex Salts [M 1(NH3)6][M 2(C2O4)3]·3H2O (M 1 = Co, Ir, M 2 = Fe, Cr)

K. V. Yusenko; S. I. Pechenyuk; E. S. Vikulova; Yu P. Semushina; I. A. Baidina; E. Yu Filatov

doi:10.1134/S0022476619070060

Isostructurality and Thermal Properties in the Series of Double Complex Salts [M ¹(NH₃)₆][M ²(C₂O₄)₃]·3H₂O (M ¹ = Co, Ir, M ² = Fe, Cr)

K. V. Yusenko, S. I. Pechenyuk, E. S. Vikulova, Yu P. Semushina, I. A. Baidina, E. Yu Filatov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

A series of four isostructural double complex salts are prepared on the basis of [M¹(NH₃)₆]³⁺ cations and [M²(C₂O₄)₃]^3– anions, where M¹ = Co, Ir, M² = Fe, Cr. The salts are crystallized in a hexagonal space group P3̄c1. According to thermal analysis data, thermal stability in an atmosphere of argon (starting temperature of the decomposition of dehydrated products) of studied compounds depends on the nature of the complex tris-oxalate anion and increases in the series [M¹(NH₃)₆][Co(C₂O₄)₃] < [M¹(NH₃)₆][Fe(C₂O₄)₃] < [M¹(NH₃)₆][Cr(C₂O₄)₃] < [M¹(NH₃)₆][Ir(C₂O₄)₃] (M¹ = Co, Ir). Hexammineiridium(III) salts are more stable than cobalt(III) salts with the same anion. Thermal decomposition of [Co(NH₃)₆][Fe(C₂O₄)₃]·3H₂O and [Ir(NH₃)₆][Fe(C₂O₄)₃]·3H₂O salts in an atmosphere of hydrogen leads to the formation of solid solutions Co_0.5Fe_0.5 and Ir_0.5Fe_0.5, respectively.

Язык оригинала	английский
Страницы (с-по)	1062-1071
Число страниц	10
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	7
DOI	https://doi.org/10.1134/S0022476619070060
Состояние	Опубликовано - 1 июл 2019

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10.1134/S0022476619070060

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@article{077e918dd9c140889c4eea003052be3b,

title = "Isostructurality and Thermal Properties in the Series of Double Complex Salts [M 1(NH3)6][M 2(C2O4)3]·3H2O (M 1 = Co, Ir, M 2 = Fe, Cr)",

abstract = "A series of four isostructural double complex salts are prepared on the basis of [M1(NH3)6]3+ cations and [M2(C2O4)3]3– anions, where M1 = Co, Ir, M2 = Fe, Cr. The salts are crystallized in a hexagonal space group P{\=3}c1. According to thermal analysis data, thermal stability in an atmosphere of argon (starting temperature of the decomposition of dehydrated products) of studied compounds depends on the nature of the complex tris-oxalate anion and increases in the series [M1(NH3)6][Co(C2O4)3] < [M1(NH3)6][Fe(C2O4)3] < [M1(NH3)6][Cr(C2O4)3] < [M1(NH3)6][Ir(C2O4)3] (M1 = Co, Ir). Hexammineiridium(III) salts are more stable than cobalt(III) salts with the same anion. Thermal decomposition of [Co(NH3)6][Fe(C2O4)3]·3H2O and [Ir(NH3)6][Fe(C2O4)3]·3H2O salts in an atmosphere of hydrogen leads to the formation of solid solutions Co0.5Fe0.5 and Ir0.5Fe0.5, respectively.",

keywords = "ammine complexes, chrome, cobalt, differential thermal analysis, double complex salts, iridium, iron, oxalate complexes, XRD analysis, DECOMPOSITION, PRECURSORS",

author = "Yusenko, {K. V.} and Pechenyuk, {S. I.} and Vikulova, {E. S.} and Semushina, {Yu P.} and Baidina, {I. A.} and Filatov, {E. Yu}",

year = "2019",

month = jul,

day = "1",

doi = "10.1134/S0022476619070060",

language = "English",

volume = "60",

pages = "1062--1071",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "7",

}

Isostructurality and Thermal Properties in the Series of Double Complex Salts [M ¹(NH₃)₆][M ²(C₂O₄)₃]·3H₂O (M ¹ = Co, Ir, M ² = Fe, Cr). / Yusenko, K. V.; Pechenyuk, S. I.; Vikulova, E. S.; Semushina, Yu P.; Baidina, I. A.; Filatov, E. Yu.

В: Journal of Structural Chemistry, Том 60, № 7, 01.07.2019, стр. 1062-1071.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Isostructurality and Thermal Properties in the Series of Double Complex Salts [M 1(NH3)6][M 2(C2O4)3]·3H2O (M 1 = Co, Ir, M 2 = Fe, Cr)

AU - Yusenko, K. V.

AU - Pechenyuk, S. I.

AU - Vikulova, E. S.

AU - Semushina, Yu P.

AU - Baidina, I. A.

AU - Filatov, E. Yu

PY - 2019/7/1

Y1 - 2019/7/1

N2 - A series of four isostructural double complex salts are prepared on the basis of [M1(NH3)6]3+ cations and [M2(C2O4)3]3– anions, where M1 = Co, Ir, M2 = Fe, Cr. The salts are crystallized in a hexagonal space group P3̄c1. According to thermal analysis data, thermal stability in an atmosphere of argon (starting temperature of the decomposition of dehydrated products) of studied compounds depends on the nature of the complex tris-oxalate anion and increases in the series [M1(NH3)6][Co(C2O4)3] < [M1(NH3)6][Fe(C2O4)3] < [M1(NH3)6][Cr(C2O4)3] < [M1(NH3)6][Ir(C2O4)3] (M1 = Co, Ir). Hexammineiridium(III) salts are more stable than cobalt(III) salts with the same anion. Thermal decomposition of [Co(NH3)6][Fe(C2O4)3]·3H2O and [Ir(NH3)6][Fe(C2O4)3]·3H2O salts in an atmosphere of hydrogen leads to the formation of solid solutions Co0.5Fe0.5 and Ir0.5Fe0.5, respectively.

AB - A series of four isostructural double complex salts are prepared on the basis of [M1(NH3)6]3+ cations and [M2(C2O4)3]3– anions, where M1 = Co, Ir, M2 = Fe, Cr. The salts are crystallized in a hexagonal space group P3̄c1. According to thermal analysis data, thermal stability in an atmosphere of argon (starting temperature of the decomposition of dehydrated products) of studied compounds depends on the nature of the complex tris-oxalate anion and increases in the series [M1(NH3)6][Co(C2O4)3] < [M1(NH3)6][Fe(C2O4)3] < [M1(NH3)6][Cr(C2O4)3] < [M1(NH3)6][Ir(C2O4)3] (M1 = Co, Ir). Hexammineiridium(III) salts are more stable than cobalt(III) salts with the same anion. Thermal decomposition of [Co(NH3)6][Fe(C2O4)3]·3H2O and [Ir(NH3)6][Fe(C2O4)3]·3H2O salts in an atmosphere of hydrogen leads to the formation of solid solutions Co0.5Fe0.5 and Ir0.5Fe0.5, respectively.

KW - ammine complexes

KW - chrome

KW - cobalt

KW - differential thermal analysis

KW - double complex salts

KW - iridium

KW - iron

KW - oxalate complexes

KW - XRD analysis

KW - DECOMPOSITION

KW - PRECURSORS

UR - http://www.scopus.com/inward/record.url?scp=85070227607&partnerID=8YFLogxK

U2 - 10.1134/S0022476619070060

DO - 10.1134/S0022476619070060

M3 - Article

AN - SCOPUS:85070227607

VL - 60

SP - 1062

EP - 1071

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 7

ER -