Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation

Danila Vasilchenko; Sergey Tkachev; Iraida Baidina; Galina Romanenko; Sergey Korenev

doi:10.1016/j.molstruc.2016.10.088

Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation

Danila Vasilchenko, Sergey Tkachev, Iraida Baidina, Galina Romanenko, Sergey Korenev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH₂ ²⁺) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO₃)₆]^2- and [Pt(C₂O₄)₂]^2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH₂ ²⁺ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H₂O)_n(NO₃)_6-n]ⁿ⁻² species.

Язык оригинала	английский
Страницы (с-по)	855-859
Число страниц	5
Журнал	Journal of Molecular Structure
Том	1130
DOI	https://doi.org/10.1016/j.molstruc.2016.10.088
Состояние	Опубликовано - 15 фев 2017

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10.1016/j.molstruc.2016.10.088

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title = "Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation",

abstract = "Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH2 2+) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH2 2+ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n−2 species.",

keywords = "Crystal structure, Diazacrown, NMR, O-ligands, Platinum, OXALATO, CRYSTAL, PRECURSORS",

author = "Danila Vasilchenko and Sergey Tkachev and Iraida Baidina and Galina Romanenko and Sergey Korenev",

year = "2017",

month = feb,

day = "15",

doi = "10.1016/j.molstruc.2016.10.088",

language = "English",

volume = "1130",

pages = "855--859",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier",

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Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation. / Vasilchenko, Danila; Tkachev, Sergey; Baidina, Iraida; Romanenko, Galina; Korenev, Sergey.

В: Journal of Molecular Structure, Том 1130, 15.02.2017, стр. 855-859.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Isolation of homoleptic platinum oxyanionic complexes with doubly protonated diazacrown cation

AU - Vasilchenko, Danila

AU - Tkachev, Sergey

AU - Baidina, Iraida

AU - Romanenko, Galina

AU - Korenev, Sergey

PY - 2017/2/15

Y1 - 2017/2/15

N2 - Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH2 2+) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH2 2+ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n−2 species.

AB - Doubly protonated diazacrown ether cation (1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane DCH2 2+) was used for the efficient isolation of the homoleptic platinum complexes [Pt(NO3)6]2- and [Pt(C2O4)2]2- to crystalline solid phases from solutions containing mixtures of related platinum complexes. DCH2 2+ molecules in nitric acid solution were shown to prevent the condensation of mononuclear [Pt(H2O)n(NO3)6-n]n−2 species.

KW - Crystal structure

KW - Diazacrown

KW - NMR

KW - O-ligands

KW - Platinum

KW - OXALATO

KW - CRYSTAL

KW - PRECURSORS

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U2 - 10.1016/j.molstruc.2016.10.088

DO - 10.1016/j.molstruc.2016.10.088

M3 - Article

AN - SCOPUS:85002948559

VL - 1130

SP - 855

EP - 859

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

ER -