Interaction of Na                         
                        9
                                                 [SbW                         
                        9
                                                 O                         
                        33
                                                 ] with Iridium(IV) Hydroxo Complexes

A. A. Mukhacheva; P. A. Abramov; M. N. Sokolov

doi:10.1134/S0022476619040164

Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes

A. A. Mukhacheva, P. A. Abramov, M. N. Sokolov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

5 Цитирования (Scopus)

Аннотация

Thermostating of the aqueous solution of Na ₉ [SbW ₉ O ₃₃ ] with K ₂ [Ir(OH) ₆ ] at 70 °C for 17 h changes the solution’s color from blue to brown. The addition of KNO ₃ to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K _5.47 Na _2.3 [Ir _0.17 Sb _0.83 W ₆ O ₂₄ ](NO ₃ ) _0.6 ·12H ₂ O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium.

Язык оригинала	английский
Страницы (с-по)	647-653
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	4
DOI	https://doi.org/10.1134/S0022476619040164
Состояние	Опубликовано - 1 апр 2019

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10.1134/S0022476619040164

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Mukhacheva, A. A., Abramov, P. A., & Sokolov, M. N. (2019). Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes. Journal of Structural Chemistry, 60(4), 647-653. https://doi.org/10.1134/S0022476619040164

Mukhacheva, A. A. ; Abramov, P. A. ; Sokolov, M. N. / Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes. В: Journal of Structural Chemistry. 2019 ; Том 60, № 4. стр. 647-653.

@article{813c3c0709d14b389598c6032e14697f,

title = "Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes",

abstract = " Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution{\textquoteright}s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium. ",

keywords = "Anderson-type anion, crystal structure, iridium, OXIDATION, ANIONS, CHLORIDE ANATION, CRYSTAL-STRUCTURE, HETEROPOLYANIONS, FRAGMENTS, KINETICS, POLYOXOMETALATE, AQUATION, HETEROPOLYTUNGSTATES",

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year = "2019",

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doi = "10.1134/S0022476619040164",

language = "English",

volume = "60",

pages = "647--653",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

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Mukhacheva, AA, Abramov, PA & Sokolov, MN 2019, 'Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes', Journal of Structural Chemistry, том. 60, № 4, стр. 647-653. https://doi.org/10.1134/S0022476619040164

Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes. / Mukhacheva, A. A.; Abramov, P. A.; Sokolov, M. N.

В: Journal of Structural Chemistry, Том 60, № 4, 01.04.2019, стр. 647-653.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Interaction of Na 9 [SbW 9 O 33 ] with Iridium(IV) Hydroxo Complexes

AU - Mukhacheva, A. A.

AU - Abramov, P. A.

AU - Sokolov, M. N.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution’s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium.

AB - Thermostating of the aqueous solution of Na 9 [SbW 9 O 33 ] with K 2 [Ir(OH) 6 ] at 70 °C for 17 h changes the solution’s color from blue to brown. The addition of KNO 3 to the reaction solution and subsequent evaporation in air causes crystallization of the products to yield yellow crystals of composition K 5.47 Na 2.3 [Ir 0.17 Sb 0.83 W 6 O 24 ](NO 3 ) 0.6 ·12H 2 O containing an Anderson-type anion [SbVW6VIO24]7− with ∼20% of antimony positions occupied by iridium.

KW - Anderson-type anion

KW - crystal structure

KW - iridium

KW - OXIDATION

KW - ANIONS

KW - CHLORIDE ANATION

KW - CRYSTAL-STRUCTURE

KW - HETEROPOLYANIONS

KW - FRAGMENTS

KW - KINETICS

KW - POLYOXOMETALATE

KW - AQUATION

KW - HETEROPOLYTUNGSTATES

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U2 - 10.1134/S0022476619040164

DO - 10.1134/S0022476619040164

M3 - Article

AN - SCOPUS:85065402030

VL - 60

SP - 647

EP - 653

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -

Mukhacheva AA, Abramov PA, Sokolov MN. Interaction of Na ₉ [SbW ₉ O ₃₃ ] with Iridium(IV) Hydroxo Complexes. Journal of Structural Chemistry. 2019 Апр. 1;60(4):647-653. https://doi.org/10.1134/S0022476619040164