@article{0f5e818423934601b8ce25850d15be2a,
title = "Influence of a synthesis method and a support nature on physicochemical and catalytic properties of supported rhodium catalysts for the partial oxidation of hydrocarbons. I. Chloride series",
abstract = "Rhodium catalysts supported on bayerite and pseudoboehmite alumina, calcined at 800 °С, were synthesized and tested in the partial oxidation of methane. Rhodium (III) chloride was used as an active component precursor. The supports and catalysts were investigated by a wide range of physicochemical methods: XRD, SEM and HR TEM, XPS and UV–vis DRS. In both cases, large rhodium particles with a coherent scattering region size of 15–19 nm are formed, and small ones with dimensions less than 1 nm. On the whole, smaller rhodium particles are formed on the bayerite oxide. The catalyst with pseudoboehmite-type support shows better results in the reaction.",
keywords = "Alumina, Catalyst characterization, Partial oxidation of hydrocarbons, Rhodium, Supported catalysts",
author = "Shefer, {K. I.} and Rogozhnikov, {V. N.} and Larina, {T. V.} and Kovtunova, {L. M.} and Stonkus, {O. A.} and Chetyrin, {I. A.} and Suprun, {E. A.} and Moroz, {E. M.}",
note = "Funding Information: Authors are grateful to Dr. A.A. Zhdanov for his assistance with elemental analysis. This work was supported by the Russian Foundation for Basic Research , project No. 19-03-00595 , and partially supported by the Ministry of Science and Higher Education of the Russian Federation within the governmental order for Boreskov Institute of Catalysis (project АААА-А21-121011390053-4 ). Publisher Copyright: {\textcopyright} 2021 Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
doi = "10.1016/j.mcat.2021.111605",
language = "English",
volume = "508",
journal = "Molecular Catalysis",
issn = "2468-8231",
publisher = "Elsevier",
}