Аннотация
Temperature dependences of the structural relaxation time τα(T) of two hydrogen-bonded glass formers, glycerol and ethanol, were investigated by depolarized light scattering technique. τα(T) of glycerol demonstrates a transition from the Arrhenius law at high temperatures to a non-Arrhenius behavior at TA ~ 366 K. Combination of derivative analysis results for τα(T) from light scattering and dielectric spectroscopes reveals this transition near ~ 200 K in the case of ethanol. The obtained values of TA are close to the temperatures below which the excess of the Landau-Placzek ratio, associated with the appearance of locally favored structures, was observed earlier.
Язык оригинала | английский |
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Страницы (с-по) | 429-434 |
Число страниц | 6 |
Журнал | Journal of Non-Crystalline Solids |
Том | 471 |
DOI | |
Состояние | Опубликовано - 1 сент. 2017 |