Аннотация
By using the time-resolved chemically induced dynamic nuclear polarization technique, we show that the neutral guanosyl radical, G(-H), formed in the reaction of guanosine-5′-monophosphate with a triplet-excited 3,3′,4,4′-tetracarboxy benzophenone in neutral aqueous solution, protonates readily at the N7 position with the formation of a new guanosyl cation radical (G+)'.
Язык оригинала | английский |
---|---|
Страницы (с-по) | 21262-21266 |
Число страниц | 5 |
Журнал | Physical Chemistry Chemical Physics |
Том | 19 |
Номер выпуска | 32 |
DOI | |
Состояние | Опубликовано - 28 авг 2017 |