Hydroxylated phosphines as ligands for chalcogenide clusters: Self assembly, transformations and stabilization

Maxim N. Sokolov, Alexander V. Anyushin, Rita Hernandez-Molina, Rosa Llusar, Manuel G. Basallote

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono-and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P-(CH2)x-OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.

Язык оригиналаанглийский
Страницы (с-по)379-392
Число страниц14
ЖурналPure and Applied Chemistry
Том89
Номер выпуска3
DOI
СостояниеОпубликовано - 1 мар 2017

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