Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}

Airat M. Kuchkaev; Nikita Y. Shmelev; Aidar M. Kuchkaev; Aleksandr V. Sukhov; Vasily M. Babaev; Khasan R. Khayarov; Artem L. Gushchin; Maxim N. Sokolov; Oleg G. Sinyashin; Dmitry G. Yakhvarov

doi:10.3390/molecules26030538

Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo₃PdS₄}

Airat M. Kuchkaev, Nikita Y. Shmelev, Aidar M. Kuchkaev, Aleksandr V. Sukhov, Vasily M. Babaev, Khasan R. Khayarov, Artem L. Gushchin, Maxim N. Sokolov, Oleg G. Sinyashin, Dmitry G. Yakhvarov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Reaction of heterometallic cubane-type cluster complexes-[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba-dibenzylideneacetone, dbbpy-4,4'-di-tert-butyl-2,2'-bipyridine, tu-thiourea, acac-acetylacetonate, py-pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.

Язык оригинала	английский
Номер статьи	538
Журнал	Molecules (Basel, Switzerland)
Том	26
Номер выпуска	3
DOI	https://doi.org/10.3390/molecules26030538
Состояние	Опубликовано - 21 янв. 2021

Предметные области OECD FOS+WOS

1.06.CQ БИОХИМИЯ И МОЛЕКУЛЯРНАЯ БИОЛОГИЯ

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10.3390/molecules26030538

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@article{7c151eaa1aa541a89170551f8f246e28,

title = "Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}",

abstract = "Reaction of heterometallic cubane-type cluster complexes-[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba-dibenzylideneacetone, dbbpy-4,4'-di-tert-butyl-2,2'-bipyridine, tu-thiourea, acac-acetylacetonate, py-pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.",

keywords = "heterometallic cubane-type clusters, molybdenum, palladium, phosphine, phosphorous acid, white phosphorus, Phosphine, Palladium, Phos-phorous acid, Molybdenum, White phosphorus, Heterometallic cubane-type clusters",

author = "Kuchkaev, {Airat M.} and Shmelev, {Nikita Y.} and Kuchkaev, {Aidar M.} and Sukhov, {Aleksandr V.} and Babaev, {Vasily M.} and Khayarov, {Khasan R.} and Gushchin, {Artem L.} and Sokolov, {Maxim N.} and Sinyashin, {Oleg G.} and Yakhvarov, {Dmitry G.}",

year = "2021",

month = jan,

day = "21",

doi = "10.3390/molecules26030538",

language = "English",

volume = "26",

journal = "Molecules",

issn = "1420-3049",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "3",

}

Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo₃PdS₄}. / Kuchkaev, Airat M.; Shmelev, Nikita Y.; Kuchkaev, Aidar M. и др.

В: Molecules (Basel, Switzerland), Том 26, № 3, 538, 21.01.2021.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Hydrolysis of Element (White) Phosphorus under the Action of Heterometallic Cubane-Type Cluster {Mo3PdS4}

AU - Kuchkaev, Airat M.

AU - Shmelev, Nikita Y.

AU - Kuchkaev, Aidar M.

AU - Sukhov, Aleksandr V.

AU - Babaev, Vasily M.

AU - Khayarov, Khasan R.

AU - Gushchin, Artem L.

AU - Sokolov, Maxim N.

AU - Sinyashin, Oleg G.

AU - Yakhvarov, Dmitry G.

PY - 2021/1/21

Y1 - 2021/1/21

N2 - Reaction of heterometallic cubane-type cluster complexes-[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba-dibenzylideneacetone, dbbpy-4,4'-di-tert-butyl-2,2'-bipyridine, tu-thiourea, acac-acetylacetonate, py-pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.

AB - Reaction of heterometallic cubane-type cluster complexes-[Mo3{Pd(dba)}S4Cl3(dbbpy)3]PF6, [Mo3{Pd(tu)}S4Cl3(dbbpy)3]Cl and [Mo3{Pd(dba)}S4(acac)3(py)3]PF6, where dba-dibenzylideneacetone, dbbpy-4,4'-di-tert-butyl-2,2'-bipyridine, tu-thiourea, acac-acetylacetonate, py-pyridine, with white phosphorus (P4) in the presence of water leads to the formation of phosphorous acid H3PO3 as the major product. The crucial role of the Pd atom in the cluster core {Mo3PdS4} has been established in the hydrolytic activation of P4 molecule. The main intermediate of the process, the cluster complex [Mo3{PdP(OH)3}S4Cl3(dbbpy)3]+ with coordinated P(OH)3 molecule and phosphine PH3, have been detected by 31P NMR spectroscopy in the reaction mixture.

KW - heterometallic cubane-type clusters

KW - molybdenum

KW - palladium

KW - phosphine

KW - phosphorous acid

KW - white phosphorus

KW - Phosphine

KW - Palladium

KW - Phos-phorous acid

KW - Molybdenum

KW - White phosphorus

KW - Heterometallic cubane-type clusters

UR - http://www.scopus.com/inward/record.url?scp=85100492332&partnerID=8YFLogxK

U2 - 10.3390/molecules26030538

DO - 10.3390/molecules26030538

M3 - Article

C2 - 33494201

AN - SCOPUS:85100492332

VL - 26

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 3

M1 - 538

ER -