Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S2CNR2)Cl2] (R = CH3, iso-C3H7; R2 = (CH2)6): Synthesis, Supramolecular Structures, and Thermal Behavior

O. V. Loseva, T. A. Rodina, A. V. Ivanov, I. A. Lutsenko, E. V. Korneeva, A. V. Gerasimenko, A. I. Smolentsev

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)


Abstract: The chemisorption binding of gold(III) by freshly precipitated binuclear zinc dithiocarbamates [Zn2(S2CNR2)4] from solutions in 2 M HCl makes it possible to obtain heteroligand complexes [Au(S2CNR2)Cl2]: R = CH3 (I), iso-C3H7 (II); R2 = (CH2)6 (III). The structural organization of complexes I, II, and III is determined by X-ray diffraction analysis (CIF files CCDC no. 1813107, 1813369, and 1813108, respectively). The distorted square–planar structure of the cis-[AuS2Cl2] chromophores shows the low-spin dsp2-hybrid state of the central gold atom. Pairwise secondary interactions Au⋅⋅⋅S between the adjacent molecules in complexes I and III result in the building of zigzag polymer chains (⋅⋅⋅[Au{S2CN(CH3)2}Cl2]⋅⋅⋅)n and binuclear aggregates [Au{S2CN(CH2)6}Cl2]2 at the supramolecular level. Complex II is presented by discrete molecules [Au{S2CN(iso-C3H7)2}Cl2]. According to the simultaneous thermal analysis data, the single final product of the thermolysis of compounds I–III is reduced elemental gold.

Язык оригиналаанглийский
Страницы (с-по)604-612
Число страниц9
ЖурналRussian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Номер выпуска10
СостояниеОпубликовано - 1 окт 2018

Fingerprint Подробные сведения о темах исследования «Heteroleptic Dithiocarbamato–Chlorido Gold(III) Complexes [Au(S<sub>2</sub>CNR<sub>2</sub>)Cl<sub>2</sub>] (R = CH<sub>3</sub>, iso-C<sub>3</sub>H<sub>7</sub>; R<sub>2</sub> = (CH<sub>2</sub>)<sub>6</sub>): Synthesis, Supramolecular Structures, and Thermal Behavior». Вместе они формируют уникальный семантический отпечаток (fingerprint).