Аннотация

In the reactions between the mononuclear [SbBr6]3- species, Br2 and various {cationBr} salts, Sb(iii) is commonly oxidized to Sb(v), and the cations play a key role in the formation of the particular bromoantimonate or polybromide-bromoantimonate frameworks of different dimensionalities (1D, 2D or even 3D). Screening this system yielded eleven novel compounds belonging to both the known and the novel structural types. The role of Br⋯Br halogen bonding was studied by DFT calculations, resulting in the estimation of its bond energy (1.1-2.9 kcal mol-1).

Язык оригиналаанглийский
Страницы (с-по)850-856
Число страниц7
ЖурналCrystEngComm
Том21
Номер выпуска5
DOI
СостояниеОпубликовано - 7 фев 2019

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