Growth, structure and physical properties of nonlinear K 2 Ba(NO 3 ) 4 crystals

K. E. Korzhneva, B. I. Kidyarov, L. I. Isaenko, D. A. Zherebtsov, V. V. Sharutin, A. P. Yelisseyev, N. V. Pervukhina, A. Yu Tarasova

Результат исследования: Научные публикации в периодических изданияхстатья

1 Цитирования (Scopus)

Аннотация

Transparent crystals of K 2 Ba(NO 3 ) 4 were obtained from water solution. The phase diagram of the Ba(NO 3 ) 2 -KNO 3 -H 2 O system was constructed on the basis of experimental data, using X-ray phase analysis. For the first time the crystal structure of K 2 Ba(NO 3 ) 4 was determined as tetragonal (I-42m) with unit cell parameters a = b = 8,3126(7) Å, c = 7,7711(6) Å, V = 536,988 Å 3 . It was found that K 2 Ba(NO 3 ) 4 is irreversibly decomposed into KNO 3 and Ba(NO 3 ) 2 with decomposition temperature 197.3 °C. K 2 Ba(NO 3 ) 4 crystal is transparent in the range of 0.25–2.2 μm, where an absorption peak with the maximum at 0.3 μm is observed. The band gap is about 5 eV.

Язык оригиналаанглийский
Страницы (с-по)52-57
Число страниц6
ЖурналJournal of Solid State Chemistry
Том274
DOI
СостояниеОпубликовано - 1 июн 2019

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