Growth, structure and physical properties of nonlinear K                         
                        2
                                                 Ba(NO                         
                        3
                                                 )                         
                        4
                                                  crystals

K. E. Korzhneva; B. I. Kidyarov; L. I. Isaenko; D. A. Zherebtsov; V. V. Sharutin; A. P. Yelisseyev; N. V. Pervukhina; A. Yu Tarasova

doi:10.1016/j.jssc.2019.01.037

Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals

K. E. Korzhneva, B. I. Kidyarov, L. I. Isaenko, D. A. Zherebtsov, V. V. Sharutin, A. P. Yelisseyev, N. V. Pervukhina, A. Yu Tarasova

Результат исследования: Научные публикации в периодических изданиях › статья

1 Цитирования (Scopus)

Аннотация

Transparent crystals of K ₂ Ba(NO ₃ ) ₄ were obtained from water solution. The phase diagram of the Ba(NO ₃ ) ₂ -KNO ₃ -H ₂ O system was constructed on the basis of experimental data, using X-ray phase analysis. For the first time the crystal structure of K ₂ Ba(NO ₃ ) ₄ was determined as tetragonal (I-42m) with unit cell parameters a = b = 8,3126(7) Å, c = 7,7711(6) Å, V = 536,988 Å ³ . It was found that K ₂ Ba(NO ₃ ) ₄ is irreversibly decomposed into KNO ₃ and Ba(NO ₃ ) ₂ with decomposition temperature 197.3 °C. K ₂ Ba(NO ₃ ) ₄ crystal is transparent in the range of 0.25–2.2 μm, where an absorption peak with the maximum at 0.3 μm is observed. The band gap is about 5 eV.

Язык оригинала	английский
Страницы (с-по)	52-57
Число страниц	6
Журнал	Journal of Solid State Chemistry
Том	274
DOI	https://doi.org/10.1016/j.jssc.2019.01.037
Состояние	Опубликовано - 1 июн 2019

Доступ к документу

10.1016/j.jssc.2019.01.037

Link to publication in Scopus

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Korzhneva, K. E., Kidyarov, B. I., Isaenko, L. I., Zherebtsov, D. A., Sharutin, V. V., Yelisseyev, A. P., Pervukhina, N. V., & Tarasova, A. Y. (2019). Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals. Journal of Solid State Chemistry, 274, 52-57. https://doi.org/10.1016/j.jssc.2019.01.037

Korzhneva, K. E. ; Kidyarov, B. I. ; Isaenko, L. I. ; Zherebtsov, D. A. ; Sharutin, V. V. ; Yelisseyev, A. P. ; Pervukhina, N. V. ; Tarasova, A. Yu. / Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals. В: Journal of Solid State Chemistry. 2019 ; Том 274. стр. 52-57.

@article{9689f432aecf41aaa46a5174b235f250,

title = "Growth, structure and physical properties of nonlinear K 2 Ba(NO 3 ) 4 crystals",

abstract = " Transparent crystals of K 2 Ba(NO 3 ) 4 were obtained from water solution. The phase diagram of the Ba(NO 3 ) 2 -KNO 3 -H 2 O system was constructed on the basis of experimental data, using X-ray phase analysis. For the first time the crystal structure of K 2 Ba(NO 3 ) 4 was determined as tetragonal (I-42m) with unit cell parameters a = b = 8,3126(7) {\AA}, c = 7,7711(6) {\AA}, V = 536,988 {\AA} 3 . It was found that K 2 Ba(NO 3 ) 4 is irreversibly decomposed into KNO 3 and Ba(NO 3 ) 2 with decomposition temperature 197.3 °C. K 2 Ba(NO 3 ) 4 crystal is transparent in the range of 0.25–2.2 μm, where an absorption peak with the maximum at 0.3 μm is observed. The band gap is about 5 eV. ",

keywords = "Crystal structure, Non-centrosymmetric K Ba(NO ) crystals, Optical transmission spectra, Thermal analyses, NITRATE, Non-centrosymmetric K2Ba(NO3)(4) crystals",

author = "Korzhneva, {K. E.} and Kidyarov, {B. I.} and Isaenko, {L. I.} and Zherebtsov, {D. A.} and Sharutin, {V. V.} and Yelisseyev, {A. P.} and Pervukhina, {N. V.} and Tarasova, {A. Yu}",

year = "2019",

month = jun,

day = "1",

doi = "10.1016/j.jssc.2019.01.037",

language = "English",

volume = "274",

pages = "52--57",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

Korzhneva, KE, Kidyarov, BI, Isaenko, LI, Zherebtsov, DA, Sharutin, VV, Yelisseyev, AP , Pervukhina, NV & Tarasova, AY 2019, 'Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals', Journal of Solid State Chemistry, том. 274, стр. 52-57. https://doi.org/10.1016/j.jssc.2019.01.037

Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals. / Korzhneva, K. E.; Kidyarov, B. I.; Isaenko, L. I.; Zherebtsov, D. A.; Sharutin, V. V.; Yelisseyev, A. P.; Pervukhina, N. V.; Tarasova, A. Yu.

В: Journal of Solid State Chemistry, Том 274, 01.06.2019, стр. 52-57.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Growth, structure and physical properties of nonlinear K 2 Ba(NO 3 ) 4 crystals

AU - Korzhneva, K. E.

AU - Kidyarov, B. I.

AU - Isaenko, L. I.

AU - Zherebtsov, D. A.

AU - Sharutin, V. V.

AU - Yelisseyev, A. P.

AU - Pervukhina, N. V.

AU - Tarasova, A. Yu

PY - 2019/6/1

Y1 - 2019/6/1

N2 - Transparent crystals of K 2 Ba(NO 3 ) 4 were obtained from water solution. The phase diagram of the Ba(NO 3 ) 2 -KNO 3 -H 2 O system was constructed on the basis of experimental data, using X-ray phase analysis. For the first time the crystal structure of K 2 Ba(NO 3 ) 4 was determined as tetragonal (I-42m) with unit cell parameters a = b = 8,3126(7) Å, c = 7,7711(6) Å, V = 536,988 Å 3 . It was found that K 2 Ba(NO 3 ) 4 is irreversibly decomposed into KNO 3 and Ba(NO 3 ) 2 with decomposition temperature 197.3 °C. K 2 Ba(NO 3 ) 4 crystal is transparent in the range of 0.25–2.2 μm, where an absorption peak with the maximum at 0.3 μm is observed. The band gap is about 5 eV.

AB - Transparent crystals of K 2 Ba(NO 3 ) 4 were obtained from water solution. The phase diagram of the Ba(NO 3 ) 2 -KNO 3 -H 2 O system was constructed on the basis of experimental data, using X-ray phase analysis. For the first time the crystal structure of K 2 Ba(NO 3 ) 4 was determined as tetragonal (I-42m) with unit cell parameters a = b = 8,3126(7) Å, c = 7,7711(6) Å, V = 536,988 Å 3 . It was found that K 2 Ba(NO 3 ) 4 is irreversibly decomposed into KNO 3 and Ba(NO 3 ) 2 with decomposition temperature 197.3 °C. K 2 Ba(NO 3 ) 4 crystal is transparent in the range of 0.25–2.2 μm, where an absorption peak with the maximum at 0.3 μm is observed. The band gap is about 5 eV.

KW - Crystal structure

KW - Non-centrosymmetric K Ba(NO ) crystals

KW - Optical transmission spectra

KW - Thermal analyses

KW - NITRATE

KW - Non-centrosymmetric K2Ba(NO3)(4) crystals

UR - http://www.scopus.com/inward/record.url?scp=85062996924&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2019.01.037

DO - 10.1016/j.jssc.2019.01.037

M3 - Article

AN - SCOPUS:85062996924

VL - 274

SP - 52

EP - 57

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

Korzhneva KE, Kidyarov BI, Isaenko LI, Zherebtsov DA, Sharutin VV, Yelisseyev AP и соавт. Growth, structure and physical properties of nonlinear K ₂ Ba(NO ₃ ) ₄ crystals. Journal of Solid State Chemistry. 2019 Июнь 1;274:52-57. https://doi.org/10.1016/j.jssc.2019.01.037