@article{ff9eb9e64d5f442aadde802e31b1c7da,
title = "Generation of a hetero spin complex from iron(Ii) iodide with redox active acenaphthene-1,2-diimine",
abstract = "The reaction of the redox active 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dppBIAN) and iron(II) iodide in acetonitrile led to a new complex [(dpp-BIAN)FeII I2 ] (1). Molecular structure of 1 was determined by the single crystal X-ray diffraction analysis. The spin state of the iron cation in complex 1 at room temperature and the magnetic behavior of 1 in the temperature range of 2–300 K were studied using Mossbauer spectroscopy and magnetic susceptibility measurements, respectively. The neutral character of dpp-BIAN in 1 was confirmed by IR and UV spectroscopy. The electrochemistry of 1 was studied in solution and solid state using cyclic voltammetry. The generation of the radical anion form of the dpp-BIAN ligand upon reduction of 1 in a CH2 Cl2 solution was monitored by EPR spectroscopy.",
keywords = "BIAN, Cyclic voltammetry, Iron(II) complex, Magnetic measurements, Molecular structure, α-diimine",
author = "Yambulatov, {Dmitriy S.} and Nikolaevskii, {Stanislav A.} and Kiskin, {Mikhail A.} and Kholin, {Kirill V.} and Khrizanforov, {Mikhail N.} and Budnikova, {Yulia G.} and Babeshkin, {Konstantin A.} and Efimov, {Nikolay N.} and Goloveshkin, {Alexander S.} and Imshennik, {Vladimir K.} and Maksimov, {Yurii V.} and Kadilenko, {Evgeny M.} and Gritsan, {Nina P.} and Eremenko, {Igor L.}",
note = "Funding Information: This research (synthesis of 1, X-ray crystallography, IR, and UV spectroscopy, magnetochemistry) was financially supported by the Russian Science Foundation (project 19-13-00436). E.M.K. acknowledges RFBR (grant 20-33-90104) for the financial support of the computational part of this paper and the Supercomputer Centre of Novosibirsk State University for computational resources. Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = may,
day = "18",
doi = "10.3390/molecules26102998",
language = "English",
volume = "26",
journal = "Molecules",
issn = "1420-3049",
publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",
number = "10",
}