@article{ca36ffcd0a884ad8bafc150016a85448,
title = "Functionalization of [Re6Q8(CN)6]4- clusters by methylation of cyanide ligands",
abstract = "Methylation of anionic cluster complexes [Re6Q8(CN)6]4- with ((CH3)3O)BF4 or CF3SO3CH3 afforded homoleptic isonitrile cluster complexes [Re6Q8(CH3NC)6]2+ (Q = S, Se, Te). The clusters were characterized by X-ray crystallography, mass spectrometry, 1H NMR, 13C NMR, 14N NMR, 15N NMR, 77Se NMR, and 125Te NMR techniques, electrochemistry, TGA, and photophysical measurements.",
keywords = "OCTAHEDRAL RHENIUM CLUSTER, PHOTOPHYSICAL PROPERTIES, LUMINESCENCE PROPERTIES, CHALCOGENIDE CLUSTERS, CRYSTAL-STRUCTURE, BUILDING-BLOCKS, EXCITED-STATE, COMPLEXES, REDOX, CORE",
author = "Mikhaylov, {Maksim A.} and Mironova, {Alina D.} and Brylev, {Konstantin A.} and Sukhikh, {Taisiya S.} and Eltsov, {Ilia V.} and Stass, {Dmitri V.} and Gushchin, {Artem L.} and Noboru Kitamura and Sokolov, {Maxim N.}",
year = "2019",
month = nov,
day = "7",
doi = "10.1039/c9nj02971k",
language = "English",
volume = "43",
pages = "16338--16348",
journal = "New Journal of Chemistry",
issn = "1144-0546",
publisher = "ROYAL SOC CHEMISTRY",
number = "41",
}