From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−

Spartak S. Yarovoy; Anton I. Smolentsev; Svetlana G. Kozlova; Nikolay B. Kompankov; Yakov M. Gayfulin; Igor P. Asanov; Vadim V. Yanshole; Yuri V. Mironov

doi:10.1039/c8cc07746k

From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]¹⁰⁻ and [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰⁻

Spartak S. Yarovoy, Anton I. Smolentsev, Svetlana G. Kozlova, Nikolay B. Kompankov, Yakov M. Gayfulin, Igor P. Asanov, Vadim V. Yanshole, Yuri V. Mironov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

4 Цитирования (Scopus)

Аннотация

Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO₃ and KCN led to the formation of the cluster complex [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]¹⁰⁻. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN³⁻ anion, as a μ₃-bridging ligand coordinated to the trigonal faces of the bitetrahedral W₆ metallocluster. A similar complex [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰⁻ containing μ₃-As³⁻ ligands instead of μ₃-CCN³⁻ ones has been synthesized by the reaction between WO₃, As and KCN.

Язык оригинала	английский
Страницы (с-по)	13837-13840
Число страниц	4
Журнал	Chemical Communications
Том	54
Номер выпуска	98
DOI	https://doi.org/10.1039/c8cc07746k
Состояние	Опубликовано - 21 дек. 2018

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10.1039/c8cc07746k

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Yarovoy, S. S., Smolentsev, A. I., Kozlova, S. G., Kompankov, N. B., Gayfulin, Y. M., Asanov, I. P., Yanshole, V. V., & Mironov, Y. V. (2018). From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]¹⁰⁻ and [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰⁻. Chemical Communications, 54(98), 13837-13840. https://doi.org/10.1039/c8cc07746k

@article{b768f4b535ed451da807926fb0f81dfe,

title = "From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−",

abstract = "Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.",

keywords = "STRUCTURAL-CHARACTERIZATION, CYANO COMPLEXES, MOLYBDENUM",

author = "Yarovoy, {Spartak S.} and Smolentsev, {Anton I.} and Kozlova, {Svetlana G.} and Kompankov, {Nikolay B.} and Gayfulin, {Yakov M.} and Asanov, {Igor P.} and Yanshole, {Vadim V.} and Mironov, {Yuri V.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2018",

month = dec,

day = "21",

doi = "10.1039/c8cc07746k",

language = "English",

volume = "54",

pages = "13837--13840",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "98",

}

Yarovoy, SS, Smolentsev, AI, Kozlova, SG, Kompankov, NB, Gayfulin, YM, Asanov, IP, Yanshole, VV & Mironov, YV 2018, 'From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]¹⁰⁻ and [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰⁻', Chemical Communications, том. 54, № 98, стр. 13837-13840. https://doi.org/10.1039/c8cc07746k

From oxide to a new type of molecular tungsten compound : formation of bitetrahedral cluster complexes [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]¹⁰⁻ and [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰⁻. / Yarovoy, Spartak S.; Smolentsev, Anton I.; Kozlova, Svetlana G. и др.

В: Chemical Communications, Том 54, № 98, 21.12.2018, стр. 13837-13840.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - From oxide to a new type of molecular tungsten compound

T2 - formation of bitetrahedral cluster complexes [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10− and [{W6(μ4-O)2(μ3-As)4}(CN)16]10−

AU - Yarovoy, Spartak S.

AU - Smolentsev, Anton I.

AU - Kozlova, Svetlana G.

AU - Kompankov, Nikolay B.

AU - Gayfulin, Yakov M.

AU - Asanov, Igor P.

AU - Yanshole, Vadim V.

AU - Mironov, Yuri V.

PY - 2018/12/21

Y1 - 2018/12/21

N2 - Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.

AB - Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W6(μ4-O)2(μ3-CCN)4}(CN)16]10−. Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3− anion, as a μ3-bridging ligand coordinated to the trigonal faces of the bitetrahedral W6 metallocluster. A similar complex [{W6(μ4-O)2(μ3-As)4}(CN)16]10− containing μ3-As3− ligands instead of μ3-CCN3− ones has been synthesized by the reaction between WO3, As and KCN.

KW - STRUCTURAL-CHARACTERIZATION

KW - CYANO COMPLEXES

KW - MOLYBDENUM

UR - http://www.scopus.com/inward/record.url?scp=85058076987&partnerID=8YFLogxK

U2 - 10.1039/c8cc07746k

DO - 10.1039/c8cc07746k

M3 - Article

C2 - 30467571

AN - SCOPUS:85058076987

VL - 54

SP - 13837

EP - 13840

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 98

ER -