Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations

Ya M. Gayfulin; D. A. Piryazev; Yu V. Mironov; N. G. Naumov

doi:10.1134/S107032841706001X

Framework coordination polymer based on the [Re₃Mo₃S₈(CN)₆]^6–heterometallic cluster anions and Cd²⁺ cations

Ya M. Gayfulin, D. A. Piryazev, Yu V. Mironov, N. G. Naumov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

A new coordination polymer, [Cd(NH₃)₄]₂{Cd[Re₃Mo₃S₈(CN)₆]}·1.5H₂O (I), was prepared by the reaction between solutions of Cd(CH₃COO)₂ · 2H₂O in aqueous ammonia and CaK₄[Re₃Mo₃S₈(CN)₆] · 8H₂O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) Å (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH₃ molecules is accompanied by sample amorphization.

Язык оригинала	английский
Страницы (с-по)	364-367
Число страниц	4
Журнал	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Том	43
Номер выпуска	6
DOI	https://doi.org/10.1134/S107032841706001X
Состояние	Опубликовано - 1 июн. 2017

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title = "Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations",

abstract = "A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) {\AA} (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.",

keywords = "cluster complex, coordination polymer, rhenium, structure, thermal stability, PRUSSIAN BLUE ANALOGS, SEPARATIONS, CATALYSIS, METAL-ORGANIC FRAMEWORKS, COMPLEXES, OPPORTUNITIES",

author = "Gayfulin, {Ya M.} and Piryazev, {D. A.} and Mironov, {Yu V.} and Naumov, {N. G.}",

year = "2017",

month = jun,

day = "1",

doi = "10.1134/S107032841706001X",

language = "English",

volume = "43",

pages = "364--367",

journal = "Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya",

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number = "6",

}

Framework coordination polymer based on the [Re₃Mo₃S₈(CN)₆]^6–heterometallic cluster anions and Cd²⁺ cations. / Gayfulin, Ya M.; Piryazev, D. A.; Mironov, Yu V. и др.

В: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, Том 43, № 6, 01.06.2017, стр. 364-367.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Framework coordination polymer based on the [Re3Mo3S8(CN)6]6–heterometallic cluster anions and Cd2+ cations

AU - Gayfulin, Ya M.

AU - Piryazev, D. A.

AU - Mironov, Yu V.

AU - Naumov, N. G.

PY - 2017/6/1

Y1 - 2017/6/1

N2 - A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) Å (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.

AB - A new coordination polymer, [Cd(NH3)4]2{Cd[Re3Mo3S8(CN)6]}·1.5H2O (I), was prepared by the reaction between solutions of Cd(CH3COO)2 · 2H2O in aqueous ammonia and CaK4[Re3Mo3S8(CN)6] · 8H2O in water. The crystals are cubic, space group Fm3m (Prussian blue structural type); a = 15.0268(4) Å (CIF file CSD no. 431555). According to ESR data, compound I is paramagnetic, g-factor is 2.298. Thermal stability investigation by TGA and powder X-ray diffraction showed that elimination of coordinated NH3 molecules is accompanied by sample amorphization.

KW - cluster complex

KW - coordination polymer

KW - rhenium

KW - structure

KW - thermal stability

KW - PRUSSIAN BLUE ANALOGS

KW - SEPARATIONS

KW - CATALYSIS

KW - METAL-ORGANIC FRAMEWORKS

KW - COMPLEXES

KW - OPPORTUNITIES

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U2 - 10.1134/S107032841706001X

DO - 10.1134/S107032841706001X

M3 - Article

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VL - 43

SP - 364

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JO - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

JF - Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya

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