Flux growth and optical properties of K7CaY2(B5O10)3 nonlinear crystal

A. B. Kuznetsov, D. M. Ezhov, K. A. Kokh, N. G. Kononova, V. S. Shevchenko, S. V. Rashchenko, E. V. Pestryakov, V. A. Svetlichnyi, I. N. Lapin, A. E. Kokh

Результат исследования: Научные публикации в периодических изданияхстатья

7 Цитирования (Scopus)

Аннотация

Non-centrosymmetric borates K7CaY2(B5O10)3 have been synthesized by solid state reaction and the crystals were successfully grown by the top seeded solution growth method using K2O-B2O3-CaF2 flux. According to the single X-ray diffraction, the structure belongs to the R32 space group with lattice parameters a = 13.2516(2) Å and c = 14.9679(3) Å. IR, Raman, absorption spectra as well as data on melting temperature were obtained for the crystal. The short edge of UV absorption and SHG intensity comparable with KH2PO4 (KDP) suggests that this crystal is a promising nonlinear-optical material.

Язык оригиналаанглийский
Страницы (с-по)333-338
Число страниц6
ЖурналMaterials Research Bulletin
Том107
DOI
СостояниеОпубликовано - 1 ноя 2018

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