(Fe,Ni)2P allabogdanite can be an ambient pressure phase in iron meteorites

Konstantin D. Litasov, Tatyana B. Bekker, Nursultan E. Sagatov, Pavel N. Gavryushkin, Pavel G. Krinitsyn, Konstantin E. Kuper

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

An orthorhombic modification of (Fe,Ni)2P, allabogdanite, found in iron meteorites was considered to be thermodynamically stable at pressures above 8 GPa and temperatures of 1673 K according to the results of recent static high-pressure and high-temperature experiments. A hexagonal polymorphic modification of (Fe,Ni)2P, barringerite, was considered to be stable at ambient conditions. Experimental investigation through the solid-state synthesis supported by ab initio calculations was carried out to clarify the stability fields of (Fe,Ni)2P polymorphs. Both experimental and theoretical studies show that Fe2P-allabogdanite is a low-temperature phase stable at ambient conditions up to a temperature of at least 773 K and, therefore, is not necessarily associated with high pressures. This is consistent with the textural relationships of allabogdanite in iron meteorites.

Язык оригиналаанглийский
Номер статьи8956
ЖурналScientific Reports
Том10
Номер выпуска1
DOI
СостояниеОпубликовано - 2 июн 2020

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