Features of Extended XPS Spectra of C2FBr0.15 Intercalate and Silver Foil

A. R. Cholach, I. P. Asanov, A. A. Bryliakova, A. V. Kalinkin, M. Yu Smirnov

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

The possibility to obtain novel data by standard electron spectroscopy and quantum chemical techniques is exemplified by C2FBr0.15 intercalate and silver foil. The features of extended X-ray photoelectron spectra are interpreted by electronic transitions in the valence band of similar unit cells. The analysis of experimental and calculated spectra reveals two states of intercalated Br2: molecular and chain-like. The interaction of Ag with NO2 at 300–520 K is limited by the formation of an oxidized state in the near-surface layer with a thickness of ∼6 A, with the metallic state of silver dominating in the Ag3d И Ag MNN spectra. Geometric parameters, states of atoms, and the character of bonds between them are consistent with the previously obtained results.

Язык оригиналаанглийский
Страницы (с-по)523-532
Число страниц10
ЖурналJournal of Structural Chemistry
Том61
Номер выпуска4
DOI
СостояниеОпубликовано - 1 апр 2020

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