Experimental and numerical study of the structure of premixed H2/CO/O2/Ar flames at atmospheric pressure

D. A. Knyazkov, A. M. Dmitriev, T. A. Bolshova, A. G. Shmakov, O. P. Korobeinichev, D. M. Markovich

Результат исследования: Научные публикации в периодических изданияхстатья по материалам конференции

Аннотация

Elaboration of a predictive and well validated kinetic mechanism for combustion of H2/CO mixtures is the key to development of advanced technologies for effective syngas burning in power generation systems. Moreover, understanding the combustion chemistry of H2/CO mixtures is a prerequisite for a comprehensive description of hydrocarbons chemistry and development of predictive chemical kinetic models for combustion of transportation fuels. In this work we report new experimental data for chemical speciation in the atmospheric pressure burner-stabilized premixed flames diluted with Ar and fuelled with H2/CO (1:1) mixture at equivalence ratios of 1 and 2. Flame sampling molecular beam mass spectrometry with soft electron ionization was used to examine the flames. Recent detailed chemical kinetic mechanisms for syngas combustion available from literature were used to simulate the experimental profiles with the CHEMKIN code. A compact kinetic mechanism including 11 species and 16 reactions was elaborated to reproduce the experimental data.

Язык оригиналаанглийский
Номер статьи012068
Число страниц5
ЖурналJournal of Physics: Conference Series
Том1382
Номер выпуска1
DOI
СостояниеОпубликовано - 28 ноя 2019
Событие3th Siberian Thermophysical Seminar, STS 2019 - Novosibirsk, Российская Федерация
Продолжительность: 27 авг 201929 авг 2019

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