Electron energy loss spectroscopy in the framework of the discrete dipole approximation

Alexander Kichigin, Maxim Yurkin

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференцийстатья в сборнике материалов конференциинаучнаярецензирование

Аннотация

Electron-energy-loss spectroscopy (EELS) is a widely used experimental technique for characterization of nanoparticles, being an extension of a standard electron microscopy. In EELS a particle under study is exposed to an electron beam and the loss of electron kinetic energy is measured after the interaction, varying the transverse position of the beam. This technique is particularly suitable for plasmonic nanoparticles, which exhibit unique optical properties caused by localized surface plasmon resonances (LSPRs). EELS excites full set of LSPRs and allows mapping them with unprecedented spatial resolution of down to 1?nm. The discrete dipole approximation (DDA) is a numerically exact method for simulating interaction of electromagnetic waves with particles of arbitrary shape and internal structure. It is based on volume-integral equation (VIE) in the frequency domain. In this work we extend the DDA to simulate EELS. We base all theoretical derivations on the VIE, in particular, the electric field of a moving electron is given as a line integral of the Green's tensor. Although the final expressions agree with classical textbooks, our approach allows us to employ the energy-budget considerations in the frequency domain. First, this framework leads to an expression for energy losses of electron moving faster than the speed of light in non-absorbing homogeneous medium (Cherenkov radiation), that is in agreement with the classical result (Frank-Tamm formula). Second, it leads to rigorous and general expressions for additional losses in the presence of a scatterer. These expressions are given as integrals over the volume of the scatterer (very convenient for the DDA) and are valid not only for the case of vacuum, but for arbitrary (even absorbing) host medium. We are working on implementing them in the open-source software package ADDA.

Язык оригиналаанглийский
Название основной публикации5th International Conference on Metamaterials and Nanophotonics, METANANO 2020
РедакторыPavel Belov, Mihail Petrov
ИздательAmerican Institute of Physics Inc.
ISBN (электронное издание)9780735440340
DOI
СостояниеОпубликовано - 8 дек 2020
Событие5th International Conference on Metamaterials and Nanophotonics, METANANO 2020 - St. Petersburg, Virtual, Российская Федерация
Продолжительность: 14 сен 202018 сен 2020

Серия публикаций

НазваниеAIP Conference Proceedings
Том2300
ISSN (печатное издание)0094-243X
ISSN (электронное издание)1551-7616

Конференция

Конференция5th International Conference on Metamaterials and Nanophotonics, METANANO 2020
СтранаРоссийская Федерация
ГородSt. Petersburg, Virtual
Период14.09.202018.09.2020

Предметные области OECD FOS+WOS

  • 2.05.PM МАТЕРИАЛОВЕДЕНИЕ, МУЛЬТИДИСЦИПЛИНАРНОЕ
  • 1.03.SY ОПТИКА
  • 1.03.UB ФИЗИКА, ПРИКЛАДНАЯ

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