Direct C–H Oxidation of Aromatic Substrates in the Presence of Biomimetic Iron Complexes

Олег Юрьевич Лякин, Евгений Павлович Талзи

Результат исследования: Публикации в книгах, отчётах, сборниках, трудах конференцийглава/разделнаучнаярецензирование

Аннотация

This chapter is dedicated to one of the most challenging areas of oxidation catalysis—direct oxidation of aromatic C–H groups. The development of environmentally friendly catalyst systems for the direct hydroxylation of aromatic hydrocarbons is an important task of modern catalysis. Biomimetic approach, based on the functional modeling of enzymes by iron complexes of a relatively simple structure, is considered as a promising approach for designing catalyst systems for direct aromatic hydroxylation, relying on nontoxic hydrogen peroxide used as the oxidant. The mechanism of catalytic performance of biomimetic systems is a question of primary importance; deep insight into this issue can both substantially rationalize the development of novel practical catalyst systems for the direct oxidation of aromatic hydrocarbons and enrich our knowledge on the mechanisms of natural metalloenzyme-mediated oxidations. In this chapter, the state-of-the-art in this area is provided, with the mechanistic part based mostly on the authors’ own works
Язык оригиналаанглийский
Название основной публикацииFrontiers of Green Catalytic Selective Oxidations
РедакторыKonstantin P. Brylyakov
Место публикацииSingapore
ИздательSpringer Singapore
Глава10
Страницы253-276
Число страниц24
ISBN (электронное издание)978-981-32-9751-7
ISBN (печатное издание)978-981-32-9750-0
DOI
СостояниеОпубликовано - 2 окт 2019

Серия публикаций

НазваниеGreen Chemistry and Sustainable Technology
ИздательSpringer, Singapore
ISSN (печатное издание)2196-6982
ISSN (электронное издание)2196-6990

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