Deactivation features of gallium-containing zeolites in the propane aromatization process

L. N. Vosmerikova, V. I. Zaikovskii, A. N. Volynkina, A. V. Vosmerikov

Результат исследования: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Аннотация

Conversion of propane to aromatic hydrocarbons on Ga-containing zeolite catalysts prepared by various methods has been examined, and their comparative stability against deactivation has been analyzed. It has been shown that the Ga-containing zeolite catalysts exhibit high activity and stability in propane conversion to aromatic hydrocarbons. Specific features of the formation of carbon deposits on the surface of Ga-containing zeolites in the propane aromatization reaction have been revealed using the techniques of temperature-programmed desorption of ammonia, low-temperature adsorption of nitrogen, differential thermal analysis, high-resolution transmission electron microscopy, and characteristic X-ray spectroscopy radiation. It has been found that the coke deposited on the catalyst has an almost homogeneous structure and is characterized by relatively low degree of polycondensation.

Язык оригиналаанглийский
Страницы (с-по)85-92
Число страниц8
ЖурналPetroleum Chemistry
Том57
Номер выпуска1
DOI
СостояниеОпубликовано - 1 янв 2017

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