DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks

S. G. Kozlova; I. V. Mirzaeva; M. R. Ryzhikov

doi:10.1016/j.ccr.2018.07.008

DABCO molecule in the M₂(C₈H₄O₄)₂·C₆H₁₂N₂ (M = Co, Ni, Cu, Zn) metal-organic frameworks

S. G. Kozlova, I. V. Mirzaeva, M. R. Ryzhikov

Результат исследования: Научные публикации в периодических изданиях › обзорная статья › рецензирование

13 Цитирования (Scopus)

Аннотация

The review reports recent progress in experimental and theoretical studies of structure and properties of the C₆H₁₂N₂ molecule (DABCO) in metal-organic frameworks M₂(C₈H₄O₄)₂ C₆H₁₂N₂, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D₃ symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

Язык оригинала	английский
Страницы (с-по)	62-74
Число страниц	13
Журнал	Coordination Chemistry Reviews
Том	376
DOI	https://doi.org/10.1016/j.ccr.2018.07.008
Состояние	Опубликовано - 1 дек 2018

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10.1016/j.ccr.2018.07.008

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title = "DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks",

abstract = "The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.",

keywords = "DABCO, M-DMOF, Mobility, Parity violation, Phase transition, Quantum tunneling, THERMODYNAMIC PROPERTIES, PHASE-TRANSITIONS, CRYSTAL-STRUCTURE, VIBRATIONAL-SPECTRA, BOSE-EINSTEIN CONDENSATION, CATALYZED SUZUKI-MIYAURA, HEAT-CAPACITIES, PARITY-SYMMETRY-BREAKING, NUCLEAR-QUADRUPOLE-RESONANCE, D-ALANINE",

author = "Kozlova, {S. G.} and Mirzaeva, {I. V.} and Ryzhikov, {M. R.}",

year = "2018",

month = dec,

day = "1",

doi = "10.1016/j.ccr.2018.07.008",

language = "English",

volume = "376",

pages = "62--74",

journal = "Coordination Chemistry Reviews",

issn = "0010-8545",

publisher = "Elsevier",

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DABCO molecule in the M₂(C₈H₄O₄)₂·C₆H₁₂N₂ (M = Co, Ni, Cu, Zn) metal-organic frameworks. / Kozlova, S. G.; Mirzaeva, I. V.; Ryzhikov, M. R.

В: Coordination Chemistry Reviews, Том 376, 01.12.2018, стр. 62-74.

Результат исследования: Научные публикации в периодических изданиях › обзорная статья › рецензирование

TY - JOUR

T1 - DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks

AU - Kozlova, S. G.

AU - Mirzaeva, I. V.

AU - Ryzhikov, M. R.

PY - 2018/12/1

Y1 - 2018/12/1

N2 - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

AB - The review reports recent progress in experimental and theoretical studies of structure and properties of the C6H12N2 molecule (DABCO) in metal-organic frameworks M2(C8H4O4)2 C6H12N2, where M = Co, Ni, Cu, Zn (M-DMOFs), as well as in the gas and crystalline phases. M-DMOFs belong to a new class of compounds which are considered promising materials for sorption, catalysis, selective separation, and demonstrate other remarkable properties. We review recent research on phase transitions and effect of guest molecules on properties of M-DMOFs. Thermodynamic and nuclear magnetic resonance studies of M-DMOFs indicate quantum tunneling between twisted forms (chiral isomers) of the DABCO molecule with D3 symmetry, which stops at certain low temperature. This opens an opportunity for study and control of balance between chiral isomers.

KW - DABCO

KW - M-DMOF

KW - Mobility

KW - Parity violation

KW - Phase transition

KW - Quantum tunneling

KW - THERMODYNAMIC PROPERTIES

KW - PHASE-TRANSITIONS

KW - CRYSTAL-STRUCTURE

KW - VIBRATIONAL-SPECTRA

KW - BOSE-EINSTEIN CONDENSATION

KW - CATALYZED SUZUKI-MIYAURA

KW - HEAT-CAPACITIES

KW - PARITY-SYMMETRY-BREAKING

KW - NUCLEAR-QUADRUPOLE-RESONANCE

KW - D-ALANINE

UR - http://www.scopus.com/inward/record.url?scp=85051390598&partnerID=8YFLogxK

U2 - 10.1016/j.ccr.2018.07.008

DO - 10.1016/j.ccr.2018.07.008

M3 - Review article

AN - SCOPUS:85051390598

VL - 376

SP - 62

EP - 74

JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

SN - 0010-8545