Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)

Mikhail Yu Afonin; Anton I. Smolentsev; Sergey N. Konchenko; Pavel A. Petrov

doi:10.1080/00958972.2014.992888

Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo₃S₄(dppe)₃X₃]⁺ (X = NCO^-, NCS^-; Dppe = 1,2-bis(diphenylphosphino)ethane)

Mikhail Yu Afonin, Anton I. Smolentsev, Sergey N. Konchenko, Pavel A. Petrov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Two pseudohalido-substituted cluster complexes, [Mo₃S₄(dppe)₃(NCS)₃]NCS (1) and [Mo₃S₄(dppe)₃(NCO)₃]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo₃S₄(dppe)₃Br₃]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C₆H₅CH₃ and 2·2.5C₆H₅CH₃) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo₃S₄(dppe)₃X₃]⁺, NCS^- or Br^- anions, and solvate toluene molecules.

Язык оригинала	английский
Страницы (с-по)	422-431
Число страниц	10
Журнал	Journal of Coordination Chemistry
Том	68
Номер выпуска	3
DOI	https://doi.org/10.1080/00958972.2014.992888
Состояние	Опубликовано - 1 февр. 2015

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10.1080/00958972.2014.992888

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@article{690dbc4db79548678aad7bf4da151d5e,

title = "Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)",

abstract = "Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.",

keywords = "Chalcogenides, Crystal structure, Mass-spectrometry, Molybdenum, Pseudohalides, Triangular clusters",

author = "Afonin, {Mikhail Yu} and Smolentsev, {Anton I.} and Konchenko, {Sergey N.} and Petrov, {Pavel A.}",

year = "2015",

month = feb,

day = "1",

doi = "10.1080/00958972.2014.992888",

language = "English",

volume = "68",

pages = "422--431",

journal = "Journal of Coordination Chemistry",

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publisher = "Taylor and Francis Ltd.",

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}

Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo₃S₄(dppe)₃X₃]⁺ (X = NCO^-, NCS^-; Dppe = 1,2-bis(diphenylphosphino)ethane). / Afonin, Mikhail Yu; Smolentsev, Anton I.; Konchenko, Sergey N. и др.

В: Journal of Coordination Chemistry, Том 68, № 3, 01.02.2015, стр. 422-431.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Cyanato-and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; Dppe = 1,2-bis(diphenylphosphino)ethane)

AU - Afonin, Mikhail Yu

AU - Smolentsev, Anton I.

AU - Konchenko, Sergey N.

AU - Petrov, Pavel A.

PY - 2015/2/1

Y1 - 2015/2/1

N2 - Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.

AB - Two pseudohalido-substituted cluster complexes, [Mo3S4(dppe)3(NCS)3]NCS (1) and [Mo3S4(dppe)3(NCO)3]Br (2) (dppe = 1,2-bis(diphenylphosphino)ethane), have been synthesized by substitution between [Mo3S4(dppe)3Br3]Br and potassium thiocyanate or sodium cyanate, respectively, in boiling acetonitrile. The compounds were characterized by IR-spectroscopy, elemental analysis, electrospray mass-spectrometry, and single-crystal X-ray diffraction analysis. Both compounds crystallize as toluene solvates (1·3C6H5CH3 and 2·2.5C6H5CH3) in space group with similar unit cell dimensions and adopt very similar molecular geometries. Both structures consist of discrete cluster cations [Mo3S4(dppe)3X3]+, NCS- or Br- anions, and solvate toluene molecules.

KW - Chalcogenides

KW - Crystal structure

KW - Mass-spectrometry

KW - Molybdenum

KW - Pseudohalides

KW - Triangular clusters

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U2 - 10.1080/00958972.2014.992888

DO - 10.1080/00958972.2014.992888

M3 - Article

AN - SCOPUS:84943610058

VL - 68

SP - 422

EP - 431

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 3

ER -