Cu2ZnSnS4crystal growth using an SnCl2based flux

K. A. Kokh; V. V. Atuchin; S. V. Adichtchev; T. A. Gavrilova; A. M. Bakhadur; A. O. Klimov; I. V. Korolkov; N. V. Kuratieva; S. Mukherjee; N. V. Pervukhina; N. V. Surovtsev

doi:10.1039/d0ce01264e

Cu₂ZnSnS₄crystal growth using an SnCl₂based flux

K. A. Kokh, V. V. Atuchin, S. V. Adichtchev, T. A. Gavrilova, A. M. Bakhadur, A. O. Klimov, I. V. Korolkov, N. V. Kuratieva, S. Mukherjee, N. V. Pervukhina, N. V. Surovtsev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The stoichiometry and phase homogeneity of the kesterite type compound Cu₂ZnSnS₄play a key role in its efficiency in solar cells. In this work, CuCl₂, ZnCl₂and SnCl₂were applied as solvents in the Cu₂ZnSnS₄crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl₂presented a single-phase Zn-rich kesterite with composition Cu_1.94Zn_1.06SnS₄and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) Å. The crystal structure of Cu_1.94Zn_1.06SnS₄was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl₂solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm⁻¹line was as low as 9.6 cm⁻¹that indicates the minimal lattice disorder.

Язык оригинала	английский
Страницы (с-по)	1025-1032
Число страниц	8
Журнал	CrystEngComm
Том	23
Номер выпуска	4
DOI	https://doi.org/10.1039/d0ce01264e
Состояние	Опубликовано - 28 янв 2021

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10.1039/d0ce01264e

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@article{c4df960071a2428c9b09603630f4c1f4,

title = "Cu2ZnSnS4crystal growth using an SnCl2based flux",

abstract = "The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) {\AA}. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.",

author = "Kokh, {K. A.} and Atuchin, {V. V.} and Adichtchev, {S. V.} and Gavrilova, {T. A.} and Bakhadur, {A. M.} and Klimov, {A. O.} and Korolkov, {I. V.} and Kuratieva, {N. V.} and S. Mukherjee and Pervukhina, {N. V.} and Surovtsev, {N. V.}",

note = "Funding Information: This work was supported by the Russian Science Foundation (project 19-42-02003), the Ministry of Science and Higher Education of Russia (projects 075-15-2020-797 (13.1902.21.0024) and AAAA-A17-117052410033-9), the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), state assignment of IGM SB RAS, and the DST-RSF Bilateral Project (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2021",

month = jan,

day = "28",

doi = "10.1039/d0ce01264e",

language = "English",

volume = "23",

pages = "1025--1032",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "4",

}

Cu₂ZnSnS₄crystal growth using an SnCl₂based flux. / Kokh, K. A.; Atuchin, V. V.; Adichtchev, S. V.; Gavrilova, T. A.; Bakhadur, A. M.; Klimov, A. O.; Korolkov, I. V.; Kuratieva, N. V.; Mukherjee, S.; Pervukhina, N. V.; Surovtsev, N. V.

В: CrystEngComm, Том 23, № 4, 28.01.2021, стр. 1025-1032.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Cu2ZnSnS4crystal growth using an SnCl2based flux

AU - Kokh, K. A.

AU - Atuchin, V. V.

AU - Adichtchev, S. V.

AU - Gavrilova, T. A.

AU - Bakhadur, A. M.

AU - Klimov, A. O.

AU - Korolkov, I. V.

AU - Kuratieva, N. V.

AU - Mukherjee, S.

AU - Pervukhina, N. V.

AU - Surovtsev, N. V.

N1 - Funding Information: This work was supported by the Russian Science Foundation (project 19-42-02003), the Ministry of Science and Higher Education of Russia (projects 075-15-2020-797 (13.1902.21.0024) and AAAA-A17-117052410033-9), the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No. AP08052719), state assignment of IGM SB RAS, and the DST-RSF Bilateral Project (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Publisher Copyright: © The Royal Society of Chemistry 2021. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/28

Y1 - 2021/1/28

N2 - The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) Å. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.

AB - The stoichiometry and phase homogeneity of the kesterite type compound Cu2ZnSnS4play a key role in its efficiency in solar cells. In this work, CuCl2, ZnCl2and SnCl2were applied as solvents in the Cu2ZnSnS4crystal growth for the first time. The multiphase ingot was obtained by direct fusion of the stoichiometric batch composed of constituent elements. Compared to that, the material recrystallized in SnCl2presented a single-phase Zn-rich kesterite with composition Cu1.94Zn1.06SnS4and unit cell parameters ofa= 5.4324(3) andc= 10.8383(2) Å. The crystal structure of Cu1.94Zn1.06SnS4was determined by single crystal X-ray diffraction analysis. The integral phase purity of the crystals grown with the use of the SnCl2solvent was verified by powder X-ray diffraction analysis and Raman measurements. In the Raman spectrum, the FWHM value of the 337 cm−1line was as low as 9.6 cm−1that indicates the minimal lattice disorder.

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U2 - 10.1039/d0ce01264e

DO - 10.1039/d0ce01264e

M3 - Article

AN - SCOPUS:85100278135

VL - 23

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EP - 1032

JO - CrystEngComm

JF - CrystEngComm

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