CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties

A. V. Artem’ev; M. I. Rakhmanova; D. G. Samsonenko

doi:10.1134/S0022476619040127

CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties

A. V. Artem’ev, M. I. Rakhmanova, D. G. Samsonenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu ₂ I ₂ (L)] _n in a 75% yield. The latter consists of double-stranded (Cu ₂ I ₂ ) _n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λ _max = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%).

Язык оригинала	английский
Страницы (с-по)	617-622
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	4
DOI	https://doi.org/10.1134/S0022476619040127
Состояние	Опубликовано - 1 апр 2019

Доступ к документу

10.1134/S0022476619040127

Link to publication in Scopus

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Цитировать

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title = "CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties",

abstract = " 2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu 2 I 2 (L)] n in a 75% yield. The latter consists of double-stranded (Cu 2 I 2 ) n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λ max = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%). ",

keywords = "coordination polymers, copper(I), crystal structure, luminescence, pyridine ligands, thioethers, CLUSTERS, COMPLEXES",

author = "Artem{\textquoteright}ev, {A. V.} and Rakhmanova, {M. I.} and Samsonenko, {D. G.}",

year = "2019",

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CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand : Synthesis and Luminescent Properties. / Artem’ev, A. V.; Rakhmanova, M. I.; Samsonenko, D. G.

В: Journal of Structural Chemistry, Том 60, № 4, 01.04.2019, стр. 617-622.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand

T2 - Synthesis and Luminescent Properties

AU - Artem’ev, A. V.

AU - Rakhmanova, M. I.

AU - Samsonenko, D. G.

PY - 2019/4/1

Y1 - 2019/4/1

N2 - 2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu 2 I 2 (L)] n in a 75% yield. The latter consists of double-stranded (Cu 2 I 2 ) n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λ max = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%).

AB - 2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu 2 I 2 (L)] n in a 75% yield. The latter consists of double-stranded (Cu 2 I 2 ) n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λ max = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%).

KW - coordination polymers

KW - copper(I)

KW - crystal structure

KW - luminescence

KW - pyridine ligands

KW - thioethers

KW - CLUSTERS

KW - COMPLEXES

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U2 - 10.1134/S0022476619040127

DO - 10.1134/S0022476619040127

M3 - Article

AN - SCOPUS:85065447050

VL - 60

SP - 617

EP - 622

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

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