Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko; E. Yu Semitut; E. A. Bykova; S. V. Korenev

doi:10.1134/S0022476617010127

Crystal structures of [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko, E. Yu Semitut, E. A. Bykova, S. V. Korenev

Результат исследования: Научные публикации в периодических изданиях › статья

Аннотация

New double complex salts [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl₄]^– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

Язык оригинала	английский
Страницы (с-по)	84-89
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	1
DOI	https://doi.org/10.1134/S0022476617010127
Состояние	Опубликовано - 1 янв 2017

Доступ к документу

10.1134/S0022476617010127

Link to publication in Scopus

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Цитировать

Vasilchenko, D. B., Semitut, E. Y., Bykova, E. A., & Korenev, S. V. (2017). Crystal structures of [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) complex salts. Journal of Structural Chemistry, 58(1), 84-89. https://doi.org/10.1134/S0022476617010127

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abstract = "New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.",

keywords = "gold, picoline, pyridine, rhodium, single crystal X-ray diffraction analysis, synthesis, THERMAL-PROPERTIES, CL, METAL, PRECURSORS",

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Crystal structures of [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) complex salts. / Vasilchenko, D. B.; Semitut, E. Yu; Bykova, E. A.; Korenev, S. V.

В: Journal of Structural Chemistry, Том 58, № 1, 01.01.2017, стр. 84-89.

Результат исследования: Научные публикации в периодических изданиях › статья

TY - JOUR

T1 - Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

AU - Vasilchenko, D. B.

AU - Semitut, E. Yu

AU - Bykova, E. A.

AU - Korenev, S. V.

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AB - New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

KW - gold

KW - picoline

KW - pyridine

KW - rhodium

KW - single crystal X-ray diffraction analysis

KW - synthesis

KW - THERMAL-PROPERTIES

KW - CL

KW - METAL

KW - PRECURSORS

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JO - Journal of Structural Chemistry

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