Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko; E. Yu Semitut; E. A. Bykova; S. V. Korenev

doi:10.1134/S0022476617010127

Crystal structures of [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) complex salts

D. B. Vasilchenko, E. Yu Semitut, E. A. Bykova, S. V. Korenev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

New double complex salts [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl₄]^– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

Язык оригинала	английский
Страницы (с-по)	84-89
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	1
DOI	https://doi.org/10.1134/S0022476617010127
Состояние	Опубликовано - 1 янв 2017

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10.1134/S0022476617010127

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abstract = "New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.",

keywords = "gold, picoline, pyridine, rhodium, single crystal X-ray diffraction analysis, synthesis, THERMAL-PROPERTIES, CL, METAL, PRECURSORS",

author = "Vasilchenko, {D. B.} and Semitut, {E. Yu} and Bykova, {E. A.} and Korenev, {S. V.}",

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Crystal structures of [RhL₄Cl₂][AuCl₄] (L = Py, γ- and β-picolines) complex salts. / Vasilchenko, D. B.; Semitut, E. Yu; Bykova, E. A.; Korenev, S. V.

В: Journal of Structural Chemistry, Том 58, № 1, 01.01.2017, стр. 84-89.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structures of [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) complex salts

AU - Vasilchenko, D. B.

AU - Semitut, E. Yu

AU - Bykova, E. A.

AU - Korenev, S. V.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

AB - New double complex salts [RhL4Cl2][AuCl4] (L = Py, γ- and β-picolines) are synthesized. The compounds are characterized by elemental, powder and single crystal X-ray diffraction analyses. The salts crystallize in different space groups. A specific feature of the packing of [AuCl4]– complex anions is the chain formation due to additional Au…Cl or Cl…Cl contacts.

KW - gold

KW - picoline

KW - pyridine

KW - rhodium

KW - single crystal X-ray diffraction analysis

KW - synthesis

KW - THERMAL-PROPERTIES

KW - CL

KW - METAL

KW - PRECURSORS

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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