Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y2SiO4Q (Q = S, Se)

A. S. Kiryakov; D. A. Piryazev; M. S. Tarasenko; N. G. Naumov

doi:10.1134/S0022476618030186

Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y₂SiO₄Q (Q = S, Se)

A. S. Kiryakov, D. A. Piryazev, M. S. Tarasenko, N. G. Naumov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

Compounds Y₂SiO₄Q (Q = S, Se) are obtained by the interaction of oxides and elemental substances in cesium chloride flux. The structures of these compounds are determined by the single crystal XRD analysis. These compounds isostructural and crystallize in the space group Pbcm with the following parameters: Y₂SiO₄S (I) a = 6.0462(8) Å, b = 6.8976(9) Å, c = 10.6558(13) Å, V = 444.39(10) Å³; Y₂SiO₄Se (II) a = 5.9935(7) Å, b = 6.9216(8) Å, c = 10.7688(12) Å, V = 446.74(9) Å³. The measured fluxing points are 1650±15 °С for I and 1850±15 °С for II.

Язык оригинала	английский
Страницы (с-по)	635-640
Число страниц	6
Журнал	Journal of Structural Chemistry
Том	59
Номер выпуска	3
DOI	https://doi.org/10.1134/S0022476618030186
Состояние	Опубликовано - 1 мая 2018

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@article{5f52efcc0c8849ab84b0b283f707123b,

title = "Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y2SiO4Q (Q = S, Se)",

abstract = "Compounds Y2SiO4Q (Q = S, Se) are obtained by the interaction of oxides and elemental substances in cesium chloride flux. The structures of these compounds are determined by the single crystal XRD analysis. These compounds isostructural and crystallize in the space group Pbcm with the following parameters: Y2SiO4S (I) a = 6.0462(8) {\AA}, b = 6.8976(9) {\AA}, c = 10.6558(13) {\AA}, V = 444.39(10) {\AA}3; Y2SiO4Se (II) a = 5.9935(7) {\AA}, b = 6.9216(8) {\AA}, c = 10.7688(12) {\AA}, V = 446.74(9) {\AA}3. The measured fluxing points are 1650±15 °С for I and 1850±15 °С for II.",

keywords = "chalcogenide, crystal structure, orthosilicate, synthesis, yttrium, LN, SELENIDE, RECENT PROGRESS, TELLURIDE",

author = "Kiryakov, {A. S.} and Piryazev, {D. A.} and Tarasenko, {M. S.} and Naumov, {N. G.}",

year = "2018",

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language = "English",

volume = "59",

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Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y₂SiO₄Q (Q = S, Se). / Kiryakov, A. S.; Piryazev, D. A.; Tarasenko, M. S. и др.

В: Journal of Structural Chemistry, Том 59, № 3, 01.05.2018, стр. 635-640.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y2SiO4Q (Q = S, Se)

AU - Kiryakov, A. S.

AU - Piryazev, D. A.

AU - Tarasenko, M. S.

AU - Naumov, N. G.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - Compounds Y2SiO4Q (Q = S, Se) are obtained by the interaction of oxides and elemental substances in cesium chloride flux. The structures of these compounds are determined by the single crystal XRD analysis. These compounds isostructural and crystallize in the space group Pbcm with the following parameters: Y2SiO4S (I) a = 6.0462(8) Å, b = 6.8976(9) Å, c = 10.6558(13) Å, V = 444.39(10) Å3; Y2SiO4Se (II) a = 5.9935(7) Å, b = 6.9216(8) Å, c = 10.7688(12) Å, V = 446.74(9) Å3. The measured fluxing points are 1650±15 °С for I and 1850±15 °С for II.

AB - Compounds Y2SiO4Q (Q = S, Se) are obtained by the interaction of oxides and elemental substances in cesium chloride flux. The structures of these compounds are determined by the single crystal XRD analysis. These compounds isostructural and crystallize in the space group Pbcm with the following parameters: Y2SiO4S (I) a = 6.0462(8) Å, b = 6.8976(9) Å, c = 10.6558(13) Å, V = 444.39(10) Å3; Y2SiO4Se (II) a = 5.9935(7) Å, b = 6.9216(8) Å, c = 10.7688(12) Å, V = 446.74(9) Å3. The measured fluxing points are 1650±15 °С for I and 1850±15 °С for II.

KW - chalcogenide

KW - crystal structure

KW - orthosilicate

KW - synthesis

KW - yttrium

KW - LN

KW - SELENIDE

KW - RECENT PROGRESS

KW - TELLURIDE

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DO - 10.1134/S0022476618030186

M3 - Article

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