Аннотация
The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.
Язык оригинала | английский |
---|---|
Страницы (с-по) | 90-96 |
Число страниц | 7 |
Журнал | Journal of Structural Chemistry |
Том | 58 |
Номер выпуска | 1 |
DOI | |
Состояние | Опубликовано - 1 янв. 2017 |