Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)

S. P. Khranenko; E. A. Bykova; A. V. Zadesenets; S. A. Gromilov

doi:10.1134/S0022476617010139

Crystal structures of [M(Еn)₃](ReO₄)₂ (M = Ni, Zn)

S. P. Khranenko, E. A. Bykova, A. V. Zadesenets, S. A. Gromilov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

The structures of two isostructural phases of [M(Еn)₃](ReO₄)₂ (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)₃](ReO₄)₂ (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.

Язык оригинала	английский
Страницы (с-по)	90-96
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	1
DOI	https://doi.org/10.1134/S0022476617010139
Состояние	Опубликовано - 1 янв. 2017

Доступ к документу

10.1134/S0022476617010139

Другие файлы и ссылки

Link to publication in Scopus

Цитировать

@article{464a572910ca4e64a1dc39e2c73b3409,

title = "Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)",

abstract = "The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.",

keywords = "crystal chemistry, ethylenediamine, nickel, rhenium, single crystal X-ray diffraction study, zinc, THERMOLYSIS, THERMAL-PROPERTIES, SOLID-SOLUTIONS, SALTS",

author = "Khranenko, {S. P.} and Bykova, {E. A.} and Zadesenets, {A. V.} and Gromilov, {S. A.}",

year = "2017",

month = jan,

day = "1",

doi = "10.1134/S0022476617010139",

language = "English",

volume = "58",

pages = "90--96",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "1",

}

Crystal structures of [M(Еn)₃](ReO₄)₂ (M = Ni, Zn). / Khranenko, S. P.; Bykova, E. A.; Zadesenets, A. V. и др.

В: Journal of Structural Chemistry, Том 58, № 1, 01.01.2017, стр. 90-96.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)

AU - Khranenko, S. P.

AU - Bykova, E. A.

AU - Zadesenets, A. V.

AU - Gromilov, S. A.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.

AB - The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.

KW - crystal chemistry

KW - ethylenediamine

KW - nickel

KW - rhenium

KW - single crystal X-ray diffraction study

KW - zinc

KW - THERMOLYSIS

KW - THERMAL-PROPERTIES

KW - SOLID-SOLUTIONS

KW - SALTS

UR - http://www.scopus.com/inward/record.url?scp=85016007138&partnerID=8YFLogxK

U2 - 10.1134/S0022476617010139

DO - 10.1134/S0022476617010139

M3 - Article

AN - SCOPUS:85016007138

VL - 58

SP - 90

EP - 96

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1