Crystal structures of cis-diiododiammine platinum and trans-diazidodiammine platinum

D. B. Vasilchenko, A. V. Zadesenets, I. A. Baidina, D. A. Piryazev, G. V. Romanenko

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

Platinum(II) complexes cis-[Pt(NH3)2I2] (1) and trans-[Pt(NH3)2(N3)2] (2) are structurally characterized separately for the first time. The crystallographic data are as follows: for 1, a = 7.0065(6) Å, b = 6.8714(6) Å, c = 7.4106(8) Å, β = 108.432(7)°, space group P21/m, Z = 2, ρcalc = 4.739 g/cm3; for 2, a = 8.1337(5) Å, b = 11.5821(7) Å, c = 6.9705(5) Å, β = 107.256(2)°, space group P21/c, Z = 4, ρcalc = 3.318 g/cm3. Platinum atoms have a square planar environment; the main structure-forming factor is the presence of intermolecular hydrogen bonds forming chain motifs in the structure of 1 and a threedimensional framework in the structure of 2.

Язык оригиналаанглийский
Страницы (с-по)1689-1692
Число страниц4
ЖурналJournal of Structural Chemistry
Том58
Номер выпуска8
DOI
СостояниеОпубликовано - 1 дек 2017

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