Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

P. A. Petrov; T. S. Sukhikh

doi:10.1134/S0022476618060227

Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

In the interaction of [CrCp*₂] (Cp* = η⁵-C₅Me₅) with 3,6-di-tert-butyl-o-benzoquinone (Q³⁶), mixed-ligand complexes with the respective monoanionic (SQ³⁶) and dianionic (Cat³⁶) dioxolenes [CrCp*₂][Cr₃(μ₃-O)(Cp*)(SQ³⁶)(Cat³⁶)₃] (1), [{CrCp*(Cat³⁶)}₂(μ-O)] (2), and [Cr(thf)Cp*(Cat³⁶)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

Язык оригинала	английский
Страницы (с-по)	1405-1411
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	59
Номер выпуска	6
DOI	https://doi.org/10.1134/S0022476618060227
Состояние	Опубликовано - 1 нояб. 2018

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10.1134/S0022476618060227

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title = "Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes",

abstract = "In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.",

keywords = "chromium, decamethylchromocene, quinones, single crystal XRD, SALT, REDUCTION, LIGANDS, ORGANOMETALLIC OXIDES, OXIDATION-STATES, MAGNETIC-PROPERTIES",

author = "Petrov, {P. A.} and Sukhikh, {T. S.}",

note = "Publisher Copyright: {\textcopyright} 2018, Pleiades Publishing, Ltd.",

year = "2018",

month = nov,

day = "1",

doi = "10.1134/S0022476618060227",

language = "English",

volume = "59",

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journal = "Journal of Structural Chemistry",

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TY - JOUR

T1 - Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

AU - Petrov, P. A.

AU - Sukhikh, T. S.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

AB - In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr3(μ3-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

KW - chromium

KW - decamethylchromocene

KW - quinones

KW - single crystal XRD

KW - SALT

KW - REDUCTION

KW - LIGANDS

KW - ORGANOMETALLIC OXIDES

KW - OXIDATION-STATES

KW - MAGNETIC-PROPERTIES

UR - http://www.scopus.com/inward/record.url?scp=85058464326&partnerID=8YFLogxK

U2 - 10.1134/S0022476618060227

DO - 10.1134/S0022476618060227

M3 - Article

AN - SCOPUS:85058464326

VL - 59

SP - 1405

EP - 1411

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 6

ER -

Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

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