Crystal Structures of Chromium Cyclopentadienyl Catecholate Complexes

Результат исследования: Научные публикации в периодических изданияхстатья

Аннотация

In the interaction of [CrCp*2] (Cp* = η5-C5Me5) with 3,6-di-tert-butyl-o-benzoquinone (Q36), mixed-ligand complexes with the respective monoanionic (SQ36) and dianionic (Cat36) dioxolenes [CrCp*2][Cr33-O)(Cp*)(SQ36)(Cat36)3] (1), [{CrCp*(Cat36)}2(μ-O)] (2), and [Cr(thf)Cp*(Cat36)] (3) are synthesized. Their crystal structures are determined by single crystal X-ray diffraction. The conclusions on the charge state of the central ion and ligands are drawn from the obtained data.

Язык оригиналаанглийский
Страницы (с-по)1405-1411
Число страниц7
ЖурналJournal of Structural Chemistry
Том59
Номер выпуска6
DOI
СостояниеОпубликовано - 1 ноя 2018

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