Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

S. A. Adonin; M. N. Sokolov; V. P. Fedin

doi:10.1134/S0022476619100111

Crystal Structures of Bromobismuthate Complexes ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] and (3-MePy)₂C₂[Bi₂Br₁₁](Br₃)

S. A. Adonin, M. N. Sokolov, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

2 Цитирования (Scopus)

Аннотация

By the reaction of a [BiX₆]³⁻ solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)₂C₂Br₂) the bromobismuthate complex ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] (1) is obtained, which, when kept in the Br₂ solution in HBr, transforms into ((3-MePy)₂C₂)₃ [Bi₂Br₁₁](Br₃) (2). Compounds 1 and 2 are characterized by single crystal XRD.

Язык оригинала	английский
Страницы (с-по)	1655-1659
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	10
DOI	https://doi.org/10.1134/S0022476619100111
Состояние	Опубликовано - 1 окт 2019

Доступ к документу

10.1134/S0022476619100111

Другие файлы и ссылки

Link to publication in Scopus

Fingerprint

Подробные сведения о темах исследования «Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{dea2c49bfcf64a49b287bd2875c6193a,

title = "Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)",

abstract = "By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.",

keywords = "bismuth, halide complexes, polyhalides, polynuclear complexes",

author = "Adonin, {S. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",

year = "2019",

month = oct,

day = "1",

doi = "10.1134/S0022476619100111",

language = "English",

volume = "60",

pages = "1655--1659",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "10",

}

Crystal Structures of Bromobismuthate Complexes ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] and (3-MePy)₂C₂[Bi₂Br₁₁](Br₃). / Adonin, S. A.; Sokolov, M. N.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 60, № 10, 01.10.2019, стр. 1655-1659.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

AU - Adonin, S. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

AB - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

KW - bismuth

KW - halide complexes

KW - polyhalides

KW - polynuclear complexes

UR - http://www.scopus.com/inward/record.url?scp=85074612164&partnerID=8YFLogxK

U2 - 10.1134/S0022476619100111

DO - 10.1134/S0022476619100111

M3 - Article

AN - SCOPUS:85074612164

VL - 60

SP - 1655

EP - 1659

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 10

ER -