Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

S. A. Adonin; M. N. Sokolov; V. P. Fedin

doi:10.1134/S0022476619100111

Crystal Structures of Bromobismuthate Complexes ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] and (3-MePy)₂C₂[Bi₂Br₁₁](Br₃)

S. A. Adonin, M. N. Sokolov, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

1 Цитирования (Scopus)

Аннотация

By the reaction of a [BiX₆]³⁻ solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)₂C₂Br₂) the bromobismuthate complex ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] (1) is obtained, which, when kept in the Br₂ solution in HBr, transforms into ((3-MePy)₂C₂)₃ [Bi₂Br₁₁](Br₃) (2). Compounds 1 and 2 are characterized by single crystal XRD.

Язык оригинала	английский
Страницы (с-по)	1655-1659
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	10
DOI	https://doi.org/10.1134/S0022476619100111
Состояние	Опубликовано - 1 окт 2019

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10.1134/S0022476619100111

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title = "Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)",

abstract = "By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.",

keywords = "bismuth, halide complexes, polyhalides, polynuclear complexes",

author = "Adonin, {S. A.} and Sokolov, {M. N.} and Fedin, {V. P.}",

year = "2019",

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journal = "Journal of Structural Chemistry",

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Crystal Structures of Bromobismuthate Complexes ((3-MePy)₂C₂)₄[Bi₂Br₁₁][BiBr₆] and (3-MePy)₂C₂[Bi₂Br₁₁](Br₃). / Adonin, S. A.; Sokolov, M. N.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 60, № 10, 01.10.2019, стр. 1655-1659.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structures of Bromobismuthate Complexes ((3-MePy)2C2)4[Bi2Br11][BiBr6] and (3-MePy)2C2[Bi2Br11](Br3)

AU - Adonin, S. A.

AU - Sokolov, M. N.

AU - Fedin, V. P.

PY - 2019/10/1

Y1 - 2019/10/1

N2 - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

AB - By the reaction of a [BiX6]3− solution in HBr with the bromide salt of bis-(3-methyl-1-pyridino)ethane ((3-MePy)2C2Br2) the bromobismuthate complex ((3-MePy)2C2)4[Bi2Br11][BiBr6] (1) is obtained, which, when kept in the Br2 solution in HBr, transforms into ((3-MePy)2C2)3 [Bi2Br11](Br3) (2). Compounds 1 and 2 are characterized by single crystal XRD.

KW - bismuth

KW - halide complexes

KW - polyhalides

KW - polynuclear complexes

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DO - 10.1134/S0022476619100111

M3 - Article

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SP - 1655

EP - 1659

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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