Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

A. M. Cheplakova; I. S. Fedoseev; P. V. Dorovatovskii; V. A. Lazarenko; Ya V. Zubavichus; V. N. Khrustalev; V. P. Fedin

doi:10.1134/S0022476618020348

Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C₆F₄HCO₂)₃]

A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya V. Zubavichus, V. N. Khrustalev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

6 Цитирования (Scopus)

Аннотация

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ₂-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.

Язык оригинала	английский
Страницы (с-по)	494-496
Число страниц	3
Журнал	Journal of Structural Chemistry
Том	59
Номер выпуска	2
DOI	https://doi.org/10.1134/S0022476618020348
Состояние	Опубликовано - 1 мар 2018

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10.1134/S0022476618020348

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title = "Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]",

abstract = "The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.",

keywords = "coordination polymer, crystal structure, scandium complexes, tetrafluorobenzoic acid, tetrafluoroterephthalic acid, METAL-ORGANIC FRAMEWORKS, BRIDGING LIGAND, TETRAFLUOROTEREPHTHALIC ACID, MOFS, COORDINATION POLYMERS",

author = "Cheplakova, {A. M.} and Fedoseev, {I. S.} and Dorovatovskii, {P. V.} and Lazarenko, {V. A.} and Zubavichus, {Ya V.} and Khrustalev, {V. N.} and Fedin, {V. P.}",

year = "2018",

month = mar,

day = "1",

doi = "10.1134/S0022476618020348",

language = "English",

volume = "59",

pages = "494--496",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "2",

}

Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C₆F₄HCO₂)₃]. / Cheplakova, A. M.; Fedoseev, I. S.; Dorovatovskii, P. V.; Lazarenko, V. A.; Zubavichus, Ya V.; Khrustalev, V. N.; Fedin, V. P.

В: Journal of Structural Chemistry, Том 59, № 2, 01.03.2018, стр. 494-496.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

AU - Cheplakova, A. M.

AU - Fedoseev, I. S.

AU - Dorovatovskii, P. V.

AU - Lazarenko, V. A.

AU - Zubavichus, Ya V.

AU - Khrustalev, V. N.

AU - Fedin, V. P.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.

AB - The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.

KW - coordination polymer

KW - crystal structure

KW - scandium complexes

KW - tetrafluorobenzoic acid

KW - tetrafluoroterephthalic acid

KW - METAL-ORGANIC FRAMEWORKS

KW - BRIDGING LIGAND

KW - TETRAFLUOROTEREPHTHALIC ACID

KW - MOFS

KW - COORDINATION POLYMERS

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U2 - 10.1134/S0022476618020348

DO - 10.1134/S0022476618020348

M3 - Article

AN - SCOPUS:85048144014

VL - 59

SP - 494

EP - 496

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 2

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