Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]

A. M. Cheplakova, I. S. Fedoseev, P. V. Dorovatovskii, V. A. Lazarenko, Ya V. Zubavichus, V. N. Khrustalev, V. P. Fedin

Результат исследования: Научные публикации в периодических изданияхстатья

5 Цитирования (Scopus)

Аннотация

The heating of a mixture of as-precipitated scandium hydroxide and tetrafluoroterephthalic acid in methanol is accompanied by acid decarboxylation and the formation of a tris-(2,3,5,6- tetrafluorobenzoato)scandium complex compound. According to the data of the single crystal X-ray diffraction analysis, the compound has a chain structure due to the carboxylate anion functioning as a μ2-bridging ligand. The polymer chains are linked together by interactions between the phenyl rings.

Язык оригиналаанглийский
Страницы (с-по)494-496
Число страниц3
ЖурналJournal of Structural Chemistry
Том59
Номер выпуска2
DOI
СостояниеОпубликовано - 1 мар 2018

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  • Цитировать

    Cheplakova, A. M., Fedoseev, I. S., Dorovatovskii, P. V., Lazarenko, V. A., Zubavichus, Y. V., Khrustalev, V. N., & Fedin, V. P. (2018). Crystal Structure of Tris- (2,3,5,6-Tetrafluorobenzoato)Scandium [Sc(C6F4HCO2)3]. Journal of Structural Chemistry, 59(2), 494-496. https://doi.org/10.1134/S0022476618020348