Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O

P. A. Petrov; G. A. Sosnin; D. Yu Naumov; S. N. Konchenko

doi:10.1134/S002247661504023X

Crystal structure of the seven-electron molybdenum cluster [Mo₃S₄(dppe)₃Cl₃]3.5C₄H₈O₂0.5Et₂O

P. A. Petrov, G. A. Sosnin, D. Yu Naumov, S. N. Konchenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

The seven-electron neutral cluster complex [Mo₃S₄(dppe)₃Cl₃] (dppe = Ph₂PCH₂CH₂PPh₂) is obtained by the reduction of the [Mo₃S₄(dppe)₃Cl₃]Cl cluster with gallium metal. The molecular and crystal structure of [Mo₃S₄(dppe)3Cl₃]3.5C₄H₈O₂0.5Et₂O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d _calc = 1.384 g/cm³.

Язык оригинала	английский
Страницы (с-по)	765-768
Число страниц	4
Журнал	Journal of Structural Chemistry
Том	56
Номер выпуска	4
DOI	https://doi.org/10.1134/S002247661504023X
Состояние	Опубликовано - 30 июл 2015

Доступ к документу

10.1134/S002247661504023X

Другие файлы и ссылки

Link to publication in Scopus

Fingerprint

Подробные сведения о темах исследования «Crystal structure of the seven-electron molybdenum cluster [Mo₃S₄(dppe)₃Cl₃]3.5C₄H₈O₂0.5Et₂O». Вместе они формируют уникальный семантический отпечаток (fingerprint).

Цитировать

@article{7cf4f540900b4a789a7d671f60005ffb,

title = "Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O",

abstract = "The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) {\AA}, b = 17.7178(7) {\AA}, c = 28.9609(9) {\AA}, β = 110.363(1)°, V = 19808.7(13) {\AA}3, Z = 8, d calc = 1.384 g/cm3.",

keywords = "cluster complexes, molybdenum, single crystal X-ray diffraction study, sulfur",

author = "Petrov, {P. A.} and Sosnin, {G. A.} and Naumov, {D. Yu} and Konchenko, {S. N.}",

year = "2015",

month = jul,

day = "30",

doi = "10.1134/S002247661504023X",

language = "English",

volume = "56",

pages = "765--768",

journal = "Journal of Structural Chemistry",

issn = "0022-4766",

publisher = "Springer GmbH & Co, Auslieferungs-Gesellschaf",

number = "4",

}

Crystal structure of the seven-electron molybdenum cluster [Mo₃S₄(dppe)₃Cl₃]3.5C₄H₈O₂0.5Et₂O. / Petrov, P. A.; Sosnin, G. A.; Naumov, D. Yu; Konchenko, S. N.

В: Journal of Structural Chemistry, Том 56, № 4, 30.07.2015, стр. 765-768.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O

AU - Petrov, P. A.

AU - Sosnin, G. A.

AU - Naumov, D. Yu

AU - Konchenko, S. N.

PY - 2015/7/30

Y1 - 2015/7/30

N2 - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.

AB - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.

KW - cluster complexes

KW - molybdenum

KW - single crystal X-ray diffraction study

KW - sulfur

UR - http://www.scopus.com/inward/record.url?scp=84942518556&partnerID=8YFLogxK

U2 - 10.1134/S002247661504023X

DO - 10.1134/S002247661504023X

M3 - Article

AN - SCOPUS:84942518556

VL - 56

SP - 765

EP - 768

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 4

ER -