Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O

P. A. Petrov; G. A. Sosnin; D. Yu Naumov; S. N. Konchenko

doi:10.1134/S002247661504023X

Crystal structure of the seven-electron molybdenum cluster [Mo₃S₄(dppe)₃Cl₃]3.5C₄H₈O₂0.5Et₂O

P. A. Petrov, G. A. Sosnin, D. Yu Naumov, S. N. Konchenko

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

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Аннотация

The seven-electron neutral cluster complex [Mo₃S₄(dppe)₃Cl₃] (dppe = Ph₂PCH₂CH₂PPh₂) is obtained by the reduction of the [Mo₃S₄(dppe)₃Cl₃]Cl cluster with gallium metal. The molecular and crystal structure of [Mo₃S₄(dppe)3Cl₃]3.5C₄H₈O₂0.5Et₂O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d _calc = 1.384 g/cm³.

Язык оригинала	английский
Страницы (с-по)	765-768
Число страниц	4
Журнал	Journal of Structural Chemistry
Том	56
Номер выпуска	4
DOI	https://doi.org/10.1134/S002247661504023X
Состояние	Опубликовано - 30 июл 2015

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title = "Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O",

abstract = "The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) {\AA}, b = 17.7178(7) {\AA}, c = 28.9609(9) {\AA}, β = 110.363(1)°, V = 19808.7(13) {\AA}3, Z = 8, d calc = 1.384 g/cm3.",

keywords = "cluster complexes, molybdenum, single crystal X-ray diffraction study, sulfur",

author = "Petrov, {P. A.} and Sosnin, {G. A.} and Naumov, {D. Yu} and Konchenko, {S. N.}",

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Crystal structure of the seven-electron molybdenum cluster [Mo₃S₄(dppe)₃Cl₃]3.5C₄H₈O₂0.5Et₂O. / Petrov, P. A.; Sosnin, G. A.; Naumov, D. Yu; Konchenko, S. N.

В: Journal of Structural Chemistry, Том 56, № 4, 30.07.2015, стр. 765-768.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure of the seven-electron molybdenum cluster [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O

AU - Petrov, P. A.

AU - Sosnin, G. A.

AU - Naumov, D. Yu

AU - Konchenko, S. N.

PY - 2015/7/30

Y1 - 2015/7/30

N2 - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.

AB - The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]3.5C4H8O20.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, d calc = 1.384 g/cm3.

KW - cluster complexes

KW - molybdenum

KW - single crystal X-ray diffraction study

KW - sulfur

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