Crystal Structure of Na2[OsCl6]

O. V. Rudnitskaya; E. K. Kultyshkina; E. V. Dobrokhotova; T. A. Tereshina; A. S. Popova; Ya V. Zubavichus; V. N. Khrustalev

doi:10.1134/S0022476619070096

Crystal Structure of Na₂[OsCl₆]

O. V. Rudnitskaya, E. K. Kultyshkina, E. V. Dobrokhotova, T. A. Tereshina, A. S. Popova, Ya V. Zubavichus, V. N. Khrustalev

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Salt Na₂[OsCl₆] is obtained by the interaction of H₂[OsCl₆]·H₂O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fm3̄m, a = 9.7461(11) Å, V= 925.8(3) Å³, Z = 4, R₁= 0.029, wR₂ = 0.070. The compound is characterized by UV-vis and IR spectroscopy.

Язык оригинала	английский
Страницы (с-по)	1086-1090
Число страниц	5
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	7
DOI	https://doi.org/10.1134/S0022476619070096
Состояние	Опубликовано - 1 июл. 2019
Опубликовано для внешнего пользования	Да

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10.1134/S0022476619070096

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title = "Crystal Structure of Na2[OsCl6]",

abstract = "Salt Na2[OsCl6] is obtained by the interaction of H2[OsCl6]·H2O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fm{\=3}m, a = 9.7461(11) {\AA}, V= 925.8(3) {\AA}3, Z = 4, R1= 0.029, wR2 = 0.070. The compound is characterized by UV-vis and IR spectroscopy.",

keywords = "crystal structure, osmium, osmium halide complexes, single crystal X-ray diffraction analysis, CL",

author = "Rudnitskaya, {O. V.} and Kultyshkina, {E. K.} and Dobrokhotova, {E. V.} and Tereshina, {T. A.} and Popova, {A. S.} and Zubavichus, {Ya V.} and Khrustalev, {V. N.}",

year = "2019",

month = jul,

day = "1",

doi = "10.1134/S0022476619070096",

language = "English",

volume = "60",

pages = "1086--1090",

journal = "Journal of Structural Chemistry",

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TY - JOUR

T1 - Crystal Structure of Na2[OsCl6]

AU - Rudnitskaya, O. V.

AU - Kultyshkina, E. K.

AU - Dobrokhotova, E. V.

AU - Tereshina, T. A.

AU - Popova, A. S.

AU - Zubavichus, Ya V.

AU - Khrustalev, V. N.

PY - 2019/7/1

Y1 - 2019/7/1

N2 - Salt Na2[OsCl6] is obtained by the interaction of H2[OsCl6]·H2O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fm3̄m, a = 9.7461(11) Å, V= 925.8(3) Å3, Z = 4, R1= 0.029, wR2 = 0.070. The compound is characterized by UV-vis and IR spectroscopy.

AB - Salt Na2[OsCl6] is obtained by the interaction of H2[OsCl6]·H2O with NaCl in boiling concentrated hydrochloric acid. According to the single crystal X-ray diffraction data, the substance crystallizes in the cubic system, space group Fm3̄m, a = 9.7461(11) Å, V= 925.8(3) Å3, Z = 4, R1= 0.029, wR2 = 0.070. The compound is characterized by UV-vis and IR spectroscopy.

KW - crystal structure

KW - osmium

KW - osmium halide complexes

KW - single crystal X-ray diffraction analysis

KW - CL

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U2 - 10.1134/S0022476619070096

DO - 10.1134/S0022476619070096

M3 - Article

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VL - 60

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JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

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