Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4                                                 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)

V. K. Muravieva; P. Lemoine; S. Cordier; N. G. Naumov

doi:10.1134/S002247661901013X

Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH₃)₆]₄ [{M(NH₃)₂} {Re₃Mo₃Se₈(CN)₆}₂]·15H₂O (M = Co, Ni)

V. K. Muravieva, P. Lemoine, S. Cordier, N. G. Naumov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

3 Цитирования (Scopus)

Аннотация

Two isostructural compounds of the composition [M(NH ₃ ) ₆ ] ₄ [{M(NH ₃ ) ₂ }{Re ₃ Mo ₃ Se ₈ (CN) ₆ } ₂ ]·15H ₂ O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re ₃ Mo ₃ Se ₈ (CN) ₆ ] ⁵⁻ anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH ₃ ) ₂ }{Re ₃ Mo ₃ Se ₈ (CN) ₆ }2] _∞∞ ⁸⁻ 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH ₃ ) ₆ ] ²⁺ cationic complexes inside the polymeric layer and in the interstitial space of the structure.

Язык оригинала	английский
Страницы (с-по)	99-105
Число страниц	7
Журнал	Journal of Structural Chemistry
Том	60
Номер выпуска	1
DOI	https://doi.org/10.1134/S002247661901013X
Состояние	Опубликовано - 1 янв 2019

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title = "Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)",

abstract = " Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re 3 Mo 3 Se 8 (CN) 6 ] 5− anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH 3 ) 6 ] 2+ cationic complexes inside the polymeric layer and in the interstitial space of the structure. ",

keywords = "coordination polymers, crystal structure, heterometal cluster, molybdenum, rhenium, ANIONS, FRAMEWORK MATERIALS, SE, CLUSTERS, COMPLEXES, TOOL",

author = "Muravieva, {V. K.} and P. Lemoine and S. Cordier and Naumov, {N. G.}",

year = "2019",

month = jan,

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doi = "10.1134/S002247661901013X",

language = "English",

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Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH₃)₆]₄ [{M(NH₃)₂} {Re₃Mo₃Se₈(CN)₆}₂]·15H₂O (M = Co, Ni). / Muravieva, V. K.; Lemoine, P.; Cordier, S.; Naumov, N. G.

В: Journal of Structural Chemistry, Том 60, № 1, 01.01.2019, стр. 99-105.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal Structure of Layered Cyano-Bridged Coordination Polymers [M(NH3)6]4 [{M(NH3)2} {Re3Mo3Se8(CN)6}2]·15H2O (M = Co, Ni)

AU - Muravieva, V. K.

AU - Lemoine, P.

AU - Cordier, S.

AU - Naumov, N. G.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 3 Mo 3 Se 8 (CN) 6 ] 5− 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 3 ) 6 ] 2+ Two isostructural compounds of the composition [M(NH O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH cationic complexes inside the polymeric layer and in the interstitial space of the structure.

AB - Two isostructural compounds of the composition [M(NH 3 ) 6 ] 4 [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 } 2 ]·15H 2 O (M = Co, Ni) are obtained by a reaction of a salt of heterometal cluster [Re 3 Mo 3 Se 8 (CN) 6 ] 5− anion with cobalt or nickel salts in an aqueous ammonia solution. The obtained compounds are structurally characterized. They correspond to the class of cyano-bridged coordination polymers. Two cyano groups of the octahedral cluster in the trans position form bridging bonds with Co(II) and Ni(II) cations. The obtained compounds are composed of highly charged polymeric [{M(NH 3 ) 2 }{Re 3 Mo 3 Se 8 (CN) 6 }2] ∞∞ 8− 88 layers formed by cluster anions and metal cations. The negative charge of the layers is compensated by [M(NH 3 ) 6 ] 2+ cationic complexes inside the polymeric layer and in the interstitial space of the structure.

KW - coordination polymers

KW - crystal structure

KW - heterometal cluster

KW - molybdenum

KW - rhenium

KW - ANIONS

KW - FRAMEWORK MATERIALS

KW - SE

KW - CLUSTERS

KW - COMPLEXES

KW - TOOL

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U2 - 10.1134/S002247661901013X

DO - 10.1134/S002247661901013X

M3 - Article

AN - SCOPUS:85064833461

VL - 60

SP - 99

EP - 105

JO - Journal of Structural Chemistry

JF - Journal of Structural Chemistry

SN - 0022-4766

IS - 1

ER -