Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]

Ya M. Gayfulin; A. I. Smolentsev; Yu V. Mironov; N. G. Naumov

doi:10.1134/S0022476617010292

Crystal structure of heterometallic cluster compounds K_5.3Rb_0.7[Re₃Mo₃S₈(CN)₅] and K_4.4Cs_1.6[Re₃Mo₃S₈(CN)₅]

Ya M. Gayfulin, A. I. Smolentsev, Yu V. Mironov, N. G. Naumov

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

Аннотация

Rhenium-molybdenum cluster compounds K_5.3Rb_0.7[Re₃Mo₃S₈(CN)₅] (1) and K_4.4Cs_1.6[Re₃Mo₃S₈(CN)₅] (2) are obtained by the interaction of an equimolar mixture of ReS₂ and MoS₂ with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re₃Mo₃S₈(CN)₄(CN)_2/2]^6– aligned along the a crystallographic axis and M⁺ cations located in voids of the lattice. The effect of additional Cs⁺ and Rb⁺ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

Язык оригинала	английский
Страницы (с-по)	203-206
Число страниц	4
Журнал	Journal of Structural Chemistry
Том	58
Номер выпуска	1
DOI	https://doi.org/10.1134/S0022476617010292
Состояние	Опубликовано - 1 янв. 2017

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title = "Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]",

abstract = "Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.",

keywords = "crystal structure, heterometallic cluster complex, molybdenum, polymer, rhenium, synthesis",

author = "Gayfulin, {Ya M.} and Smolentsev, {A. I.} and Mironov, {Yu V.} and Naumov, {N. G.}",

year = "2017",

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doi = "10.1134/S0022476617010292",

language = "English",

volume = "58",

pages = "203--206",

journal = "Journal of Structural Chemistry",

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}

Crystal structure of heterometallic cluster compounds K_5.3Rb_0.7[Re₃Mo₃S₈(CN)₅] and K_4.4Cs_1.6[Re₃Mo₃S₈(CN)₅]. / Gayfulin, Ya M.; Smolentsev, A. I.; Mironov, Yu V. и др.

В: Journal of Structural Chemistry, Том 58, № 1, 01.01.2017, стр. 203-206.

Результат исследования: Научные публикации в периодических изданиях › статья › рецензирование

TY - JOUR

T1 - Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]

AU - Gayfulin, Ya M.

AU - Smolentsev, A. I.

AU - Mironov, Yu V.

AU - Naumov, N. G.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

AB - Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6– aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

KW - crystal structure

KW - heterometallic cluster complex

KW - molybdenum

KW - polymer

KW - rhenium

KW - synthesis

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